Advances in the construction of diverse SuFEx linkers

D Zeng, WP Deng, X Jiang - National Science Review, 2023 - academic.oup.com
Sulfur fluoride exchange (SuFEx), a new generation of click chemistry, was first presented by
Sharpless, Dong and co-workers in 2014. Owing to the high stability and yet efficient …

Recent developments on 1, 2-difunctionalization and hydrofunctionalization of unactivated alkenes and alkynes involving C–S bond formation

B Dong, J Shen, LG Xie - Organic Chemistry Frontiers, 2023 - pubs.rsc.org
Alkenes and alkynes are feedstock compounds and key units in many natural products,
pharmaceuticals, agrochemicals, and organic functional materials. Hydrofunctionalization …

EnT-mediated N–S bond homolysis of a bifunctional reagent leading to aliphatic sulfonyl fluorides

JE Erchinger, R Hoogesteger, R Laskar… - Journal of the …, 2023 - ACS Publications
Sulfur (VI) fluoride exchange (SuFEx) gives rise to a plethora of high-valent sulfur linkages;
however, the availability of (aliphatic) sulfonyl fluoride manifolds lag behind, owing to the …

Sulfur fluoride exchange

JA Homer, L Xu, N Kayambu, Q Zheng… - Nature Reviews …, 2023 - nature.com
Click chemistry is a conceptual strategy to rapidly synthesize and discover functional
molecules. Sulfur fluoride exchange (SuFEx) is a click reaction that has revolutionized …

Radical Hydro‐Fluorosulfonylation of Unactivated Alkenes and Alkynes

P Wang, H Zhang, M Zhao, S Ji, L Lin… - Angewandte Chemie …, 2022 - Wiley Online Library
Recently, radical fluorosulfonylation is emerging as an appealing approach for the synthesis
of sulfonyl fluorides, which are highly in demand in various disciplines, particularly in …

Visible-Light-Catalyzed Tandem Radical Addition/1, 5-Hydrogen Atom Transfer/Cyclization of 2-Alkynylarylethers with Sulfonyl Chlorides

L Li, JZ Li, YB Sun, CM Luo, H Qiu, K Tang, H Liu… - Organic …, 2022 - ACS Publications
A novel visible-light-catalyzed tandem radical addition/1, 5-hydrogen atom
transfer/cyclization cascade of 2-alkynylarylethers with sulfonyl chlorides in 2 …

A practical fluorosulfonylating platform via photocatalytic imidazolium-based SO2F radical reagent

W Zhang, H Li, X Li, Z Zou, M Huang, J Liu… - Nature …, 2022 - nature.com
Sulfonyl fluorides are key components in the fields of chemical biology, materials science
and drug discovery. In this line, the highly active SO2F radical has been employed for the …

Selective fluorosulfonylation of thianthrenium salts enabled by electrochemistry

X Kong, Y Chen, Q Liu, WJ Wang, S Zhang… - Organic …, 2023 - ACS Publications
A practical electrochemically driven method for fluorosulfonylation of both aryl and alkyl
thianthrenium salts has been disclosed. The strategy does not need external redox reagents …

Photoredox catalytic radical fluorosulfonylation of olefins enabled by a bench-stable redox-active fluorosulfonyl radical precursor

P Wang, H Zhang, X Nie, T Xu, S Liao - Nature Communications, 2022 - nature.com
Sulfonyl fluorides have attracted considerable and growing research interests from various
disciplines, which raises a high demand for novel and effective methods to access this class …

Electrochemical Oxo‐Fluorosulfonylation of Alkynes under Air: Facile Access to β‐Keto Sulfonyl Fluorides

D Chen, X Nie, Q Feng, Y Zhang… - Angewandte Chemie …, 2021 - Wiley Online Library
Radical fluorosulfonylation is emerging as an appealing approach for the synthesis of
sulfonyl fluorides, which have widespread applications in many fields, in particular in the …