Phosphorus‐substituted heterocycles represent an important class of organophosphorus
compounds, which not only widely exist in biologically active pharmaceuticals …

The phosphonic acid functional group, which is characterized by a phosphorus atom
bonded to three oxygen atoms (two hydroxy groups and one P= O double bond) and one …

The asymmetric synthesis of alkynyl and monofluoroalkenyl isoindolinones from N‐methoxy
benzamides and α, α‐difluoromethylene alkynes is enabled by C− H activation with a chiral …

Abstract AH 4 SiW 12 O 40-catalyzed three-component tandem reaction of 2-acylbenzoic
acids, primary amines and phosphine oxides to form 3, 3-disubstituted isoindolinones was …

Nucleophilic substitutions such as SN 1 and SN 2 are fundamental textbook reactions. Their
stereoselective versions have been shown to be versatile in the preparation of enantiopure …

A novel organocatalytic asymmetric formal [3+ 2] cycloaddition of 3-substituted 1H-indoles
with in situ generated 3-hydroxy-isoindolinone-derived β, γ-alkynyl-α-ketimines has been …

An enantioselective aerobic decarboxylative Povarov reaction of N-aryl α-amino acids with
methylenephthalimidines through cooperative photoredox and chiral Brønsted acid catalysis …

The first enantioselective hydrophosphonylation of ketimines with phosphine oxides was
developed. The reaction of unprotected ketimines with phosphine oxides using a bis …

As important reactive species, isoindolinones represent a cluster of valuable building blocks
for the construction of natural‐product‐like compounds. In particular, chiral isoindolinones …

The catalytic enantioselective synthesis of isoindolinones was achieved through the
condensation of 2‐acyl‐benzaldehydes and anilines. In the presence of 1 mol% of a chiral …