Surface-initiated controlled radical polymerization: state-of-the-art, opportunities, and challenges in surface and interface engineering with polymer brushes

JO Zoppe, NC Ataman, P Mocny, J Wang… - Chemical …, 2017 - ACS Publications
The generation of polymer brushes by surface-initiated controlled radical polymerization (SI-
CRP) techniques has become a powerful approach to tailor the chemical and physical …

Hydration lubrication

J Klein - Friction, 2013 - Springer
The hydration lubrication paradigm, whereby hydration layers are both strongly held by the
charges they surround, and so can support large pressures without being squeezed out, and …

High lubricity meets load capacity: cartilage mimicking bilayer structure by brushing up stiff hydrogels from subsurface

M Rong, H Liu, M Scaraggi, Y Bai, L Bao… - Advanced Functional …, 2020 - Wiley Online Library
Natural articular cartilage has ultralow friction even at high squeezing pressure.
Biomimicking cartilage with soft materials has been and remains a grand challenge in the …

Brushing up functional materials

S Ma, X Zhang, B Yu, F Zhou - NPG Asia Materials, 2019 - nature.com
Surface-grafting polymer brushes (SPB), which are used in a versatile technique to easily
realize surface modifications, can be commonly used to change the inherent surface …

Lubrication at physiological pressures by polyzwitterionic brushes

M Chen, WH Briscoe, SP Armes, J Klein - science, 2009 - science.org
The very low sliding friction at natural synovial joints, which have friction coefficients of μ<
0.002 at pressures up to 5 megapascals or more, has to date not been attained in any …

Measurement of lateral adhesion forces at the interface between a liquid drop and a substrate

R Tadmor, P Bahadur, A Leh, HE N'guessan, R Jaini… - Physical review …, 2009 - APS
A novel instrument allows for the first time measurements of the lateral adhesion forces at a
solid-liquid interface, f∥, in a way that is decoupled from the normal forces, f⊥. We use it to …

Polymer-brush lubrication: a review of recent theoretical advances

T Kreer - Soft Matter, 2016 - pubs.rsc.org
This review compiles recent theoretical advances to describe compressive and shear forces
of polymer-brush bilayers, which consist of two opposing brushes in contact. Such model …

Hydration lubrication: the macromolecular domain

S Jahn, J Klein - Macromolecules, 2015 - ACS Publications
Macromolecules, which adsorb or intrinsically form boundary layers at surfaces sliding past
each other in aqueous media, are ubiquitous both in technology and in biological systems …

Molecular mechanisms of synovial joint lubrication

J Klein - Proceedings of the Institution of Mechanical …, 2006 - journals.sagepub.com
Current models for lubrication of synovial joints, and the nature of the cartilage surface, are
briefly recalled. Direct friction studies between polymers attached to surfaces are then …

Physics and applications of superhydrophobic and superhydrophilic surfaces and coatings

J Drelich, A Marmur - Surface Innovations, 2014 - icevirtuallibrary.com
The terms superhydrophobicity and superhydrophilicity were introduced not very long ago,
in 1996 and 2000, respectively. The former is used to describe exceptionally weak and the …