Catalytic developments in the epoxidation of vegetable oils and the analysis methods of epoxidized products

PT Wai, P Jiang, Y Shen, P Zhang, Q Gu, Y Leng - RSC advances, 2019 - pubs.rsc.org
Functionalization of vegetable oils (VOs) including edible, non-edible, and waste cooking oil
(WCOs) to epoxides (EVOs) is receiving great attention by many researchers from academia …

The Lord of the chemical rings: Catalytic synthesis of important industrial epoxide compounds

Y Meng, F Taddeo, AF Aguilera, X Cai, V Russo… - Catalysts, 2021 - mdpi.com
The epoxidized group, also known as the oxirane group, can be considered as one of the
most crucial rings in chemistry. Due to the high ring strain and the polarization of the C–O …

Epoxidation of linseed oil by performic acid produced in situ

R Turco, R Tesser, V Russo, T Cogliano… - Industrial & …, 2021 - ACS Publications
Linseed oil is characterized by an elevated concentration of highly unsaturated fatty acids
such as linolenic and linoleic acids. This work has the objective to evaluate the effect of the …

Influence of ring‐opening reactions on the kinetics of cottonseed oil epoxidation

X Cai, JL Zheng, AF Aguilera… - … Journal of Chemical …, 2018 - Wiley Online Library
Production of epoxidized vegetable oils becomes more and more important because they
are renewable, nontoxic, and biodegradable chemicals. At the industrial scale, the …

Kinetic modelling of Prileschajew epoxidation of oleic acid under conventional heating and microwave irradiation

AF Aguilera, P Tolvanen, K Eränen, J Wärnå… - Chemical Engineering …, 2019 - Elsevier
Epoxidation of oleic acid by peracetic acid (PAA) was studied in a recycled reactor system
under conventional heating and microwave irradiation. This reaction system consists of …

Synthesis of environment‐friendly, sustainable, and nontoxic bio‐lubricants: A critical review of advances and a path forward

SV Sancheti, GD Yadav - Biofuels, Bioproducts and Biorefining, 2022 - Wiley Online Library
Carbon neutral biosources are sought for the protection of the environment and to meet the
energy needs of the growing population. For instance, lubricants are required in huge …

Novel packed bed reactor designed for Prileschajew epoxidation of fatty acid methyl ester: Intensification of mass/heat transfer

J Cai, Z Wu, N Gao, H Xu, D Wang, F Zhou… - … and Processing-Process …, 2022 - Elsevier
In this work, a packed bed reactor with orifice plates (PBR@ OP) was designed and applied
to Prileschajew epoxidation. The reactor performance such as mass/heat transfer and …

[HTML][HTML] Ultrasound-assisted chemoenzymatic epoxidation of soybean oil by using lipase as biocatalyst

MS Bhalerao, VM Kulkarni, AV Patwardhan - Ultrasonics Sonochemistry, 2018 - Elsevier
The present work reports the use of ultrasonic irradiation for enhancing lipase catalyzed
epoxidation of soybean oil. Higher degree of unsaturated fatty acids, present in the soybean …

Catalysis for Oleochemical Platforms

ME Cucciolito, M Di Serio, R Esposito… - European Journal of …, 2023 - Wiley Online Library
The present review articles the most recent efforts, made in the Department of Chemical
Sciences of the University of Naples Federico II, in the catalytic treatment of biomasses …

Study of soybean oil epoxidation: effects of sulfuric acid and the mixing program

C Vianello, D Piccolo, A Lorenzetti… - Industrial & …, 2018 - ACS Publications
Epoxidized vegetable oils are largely employed as plasticizers instead of harmful
phthalates, and they can be a sustainable choice to produce lubricants and intermediates …