The strong light‐emission materials in the aggregated state: what happens from a single molecule to the collective group

Q Li, Z Li - Advanced science, 2017 - Wiley Online Library
The strong light emission of organic luminogens in the aggregated state is essential to their
applications as optoelectronic materials with good performance. In this review, with respect …

Hexaarylbenzene: evolution of properties and applications of multitalented scaffold

V Vij, V Bhalla, M Kumar - Chemical Reviews, 2016 - ACS Publications
The easily rotatable peripheral aromatic rings around central benzene in hexaarylbenzene
(HAB) derivatives create a very intriguing nonplanar, propeller-shaped geometry. Because …

Excited-state aromatic interactions in the aggregation-induced emission of molecular rotors

J Sturala, MK Etherington, AN Bismillah… - Journal of the …, 2017 - ACS Publications
Small, apolar aromatic groups, such as phenyl rings, are commonly included in the
structures of fluorophores to impart hindered intramolecular rotations, leading to desirable …

Deep-Saddle-Shaped Nanographene Induced by Four Heptagons: Efficient Synthesis and Properties

B Borrisov, GM Beneventi, Y Fu, Z Qiu… - Journal of the …, 2024 - ACS Publications
The construction of multiple heptagonal rings in nanographene is the key step for obtaining
exotic carbon nanostructures with a negative curvature and intriguing properties. Herein, a …

Simple and practical conversion of benzoic acids to phenols at room temperature

W Xiong, Q Shi, WH Liu - Journal of the American Chemical …, 2022 - ACS Publications
Phenols are important organic molecules because they have found widespread applications
in many fields. Herein, an efficient and practical approach to prepare phenols from benzoic …

Electronic control of the Scholl reaction: selective synthesis of spiro vs helical nanographenes

P Izquierdo‐García… - Angewandte Chemie …, 2023 - Wiley Online Library
Scholl oxidation has become an essential reaction in the bottom‐up synthesis of molecular
nanographenes. Herein, we describe a Scholl reaction controlled by the electronic effects on …

Bottom‐up Solution Synthesis of Graphene Nanoribbons with Precisely Engineered Nanopores

W Niu, Y Fu, G Serra, K Liu, J Droste… - Angewandte Chemie …, 2023 - Wiley Online Library
The incorporation of nanopores into graphene nanostructures has been demonstrated as an
efficient tool in tuning their band gaps and electronic structures. However, precisely …

Nitrate reduction enables safer aryldiazonium chemistry

J Mateos, T Schulte, D Behera, M Leutzsch, A Altun… - Science, 2024 - science.org
Aryldiazonium salts remain a staple in organic synthesis and are still prepared largely in
accord with the protocol developed in the 19th century. Because of the favorable reactivity …

Isomer Effect on Energy Storage of π‐Extended S‐Shaped Double [6] Heterohelicene

V Kumar, HJ Bharathkumar, SD Dongre… - Angewandte …, 2023 - Wiley Online Library
Recently, chiral and nonplanar cutouts of graphene have been the favorites due to their
unique optical, electronic, and redox properties and high solubility compared with their …

Probing charge management across the π-systems of nanographenes in regioisomeric electron donor–acceptor architectures

H Hölzel, P Haines, R Kaur, D Lungerich… - Journal of the …, 2022 - ACS Publications
Inspired by light-induced processes in nature to mimic the primary events in the
photosynthetic reaction centers, novel functional materials combine electron donors and …