A computational model for chemo-mechanical degradation of historical oil paintings due to metal soap formation

G Eumelen, E Bosco, ASJ Suiker, A van Loon… - Journal of the …, 2019 - Elsevier
A large percentage of oil paintings in museum collections suffers from chemo-mechanical
degradation phenomena that are primarily due to metal soap formation. Metal soaps result …

[HTML][HTML] Chemo-mechanical model for degradation of oil paintings by amorphous and crystalline metal soaps

GJAM Eumelen, E Bosco, ASJ Suiker… - European Journal of …, 2023 - Elsevier
Metal soap formation is recognised as a critical degradation mechanism in historical oil
paintings, which threatens the preservation of museum collections worldwide. Metal soaps …

Insight into the effects of moisture and layer build-up on the formation of lead soaps using micro-ATR-FTIR spectroscopic imaging of complex painted stratigraphies

E Possenti, C Colombo, M Realini, CL Song… - Analytical and …, 2021 - Springer
Metal soaps are formed in paint layers thorough the reaction of metal ions of pigments and
fatty acids of organic binders. In this study, micro-ATR-FTIR spectroscopic imaging was used …

Computational modelling of metal soap formation in historical oil paintings: the influence of fatty acid concentration and nucleus geometry on the induced chemo …

GJAM Eumelen, E Bosco, ASJ Suiker, JJ Hermans… - SN Applied …, 2020 - Springer
Metal soap formation is one of the most wide-spread degradation mechanisms observed in
historical oil paintings, affecting works of art from museum collections worldwide. Metal …

Elemental and molecular segregation in oil paintings due to lead soap degradation

YK Chen-Wiegart, J Catalano, GJ Williams, A Murphy… - Scientific reports, 2017 - nature.com
Abstract The formation of Pb, Zn, and Cu carboxylates (soaps) has caused visible
deterioration in hundreds of oil paintings dating from the 15th century to the present …

Gels for the Cleaning of Works of Art

D Chelazzi, E Fratini, R Giorgi… - Gels and other soft …, 2018 - ACS Publications
Works of art must be readable and well preserved in order to be accessible. Therefore, the
removal of unwanted layers (dirt, soil, aged adhesives and varnishes) is fundamental in …

Water Diffusion and Transport in Oil Paints as Studied by Unilateral NMR and 1H High‐Resolution MAS‐NMR Spectroscopy

V Di Tullio, N Zumbulyadis, SA Centeno… - …, 2020 - Wiley Online Library
Heavy metal carboxylate degradation severely affects thousands of oil paintings. Relative
humidity has been reported to accelerate the rate of the reactions. To evaluate its role …

Autonomous near-field communication (NFC) sensors for long-term preventive care of fine art objects

MD Steinberg, CS Kimbriel, LS d'Hont - Sensors and Actuators A: Physical, 2019 - Elsevier
We present the design and pilot trial of near-field communication (NFC) sensors for the long-
term preventive care of fine art objects. This work was undertaken to address the unmet …

[HTML][HTML] Relative humidity, light, and inorganic fillers: Defining different roles on the ageing of modern oil paints through infrared spectroscopy

R Costantini, L Nodari, J La Nasa, P Tomasin - Microchemical Journal, 2025 - Elsevier
In the past two decades, increasing attention has been paid to oil-based modern (from the
20th century onwards) binding media and their complex conservation issues, often related to …

Taking different forms: metal soaps in paintings, diagnosis of condition, and issues for treatment

A Burnstock - Metal Soaps in Art: Conservation and Research, 2019 - Springer
This chapter introduces a selection of case studies of paintings that present a range of
physical manifestations of metal soaps. The phenomena include surface spots, crusts …