Metal–organic framework-based catalysts with single metal sites

YS Wei, M Zhang, R Zou, Q Xu - Chemical Reviews, 2020 - ACS Publications
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …

Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

Ü Kökçam-Demir, A Goldman, L Esrafili… - Chemical Society …, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …

Self-sacrifice MOFs for heterogeneous catalysis: Synthesis mechanisms and future perspectives

A Ahmad, S Khan, S Tariq, R Luque, F Verpoort - Materials Today, 2022 - Elsevier
This review depicts the exposure of self-sacrifice MOF, their structure, synthesis as well as
potential application from a prodigious angle. We elaborated critically each of the self …

Mixed‐metal MOFs: unique opportunities in metal–organic framework (MOF) functionality and design

MY Masoomi, A Morsali… - Angewandte …, 2019 - Wiley Online Library
Mixed‐metal metal–organic frameworks (MM‐MOFs) can be considered to be those MOFs
having two different metals anywhere in the structure. Herein we summarize the various …

Tuning the structure and function of metal–organic frameworks via linker design

W Lu, Z Wei, ZY Gu, TF Liu, J Park, J Park… - Chemical Society …, 2014 - pubs.rsc.org
Metal–organic frameworks (MOFs) are constructed from metal ions/clusters coordinated by
organic linkers (or bridging-ligands). The hallmark of MOFs is their permanent porosity …

Metal Organic Framework Catalysis: Quo vadis?

J Gascon, A Corma, F Kapteijn… - Acs Catalysis, 2014 - ACS Publications
In this perspective, we highlight the main opportunities of metal organic frameworks (MOFs)
as heterogeneous catalysts. Along with our personal view on the most promising catalytic …

Hydrogen storage in metal–organic frameworks

MP Suh, HJ Park, TK Prasad, DW Lim - Chemical reviews, 2012 - ACS Publications
The decreasing fossil fuel supply and climate change caused by carbon dioxide emission
have spurred an initiative to develop alternative fuels. Hydrogen is one of the most …

Vanadium‐based metal‐organic frameworks and their derivatives for electrochemical energy conversion and storage

J Zhu, X Chen, AQ Thang, FL Li, D Chen, H Geng… - …, 2022 - Wiley Online Library
With the excessive consumption of nonrenewable resources, the exploration of effective and
durable materials is highly sought after in the field of sustainable energy conversion and …

Engineering metal organic frameworks for heterogeneous catalysis

A Corma, HI Garcia, FX Llabrés i Xamena - Chemical reviews, 2010 - ACS Publications
The development of surface-characterization techniques, molecular modeling, and
advanced synthesis methods have transformed the preparation of solid catalysts from an art …

Metal–organic framework materials as catalysts

JY Lee, OK Farha, J Roberts, KA Scheidt… - Chemical Society …, 2009 - pubs.rsc.org
A critical review of the emerging field of MOF-based catalysis is presented. Discussed are
examples of:(a) opportunistic catalysis with metal nodes,(b) designed catalysis with …