Using real-time mass spectrometric (MS) monitoring, we demonstrate one-step, catalyst-free
spontaneous oxidation of various alcohols (ROH) to key reactive intermediates for the …

A Ni-based catalyst is a common non-noble-metal system for CO2 methanation, and metal
modification for the support is an effective method to further improve its activity. Doping …

Attractiveness in advanced low-temperature combustion engines drives a constantly
updated understanding of low-temperature oxidation chemistry. In this work, the low …

Organic hydroperoxides (ROOH) are ubiquitous in the atmospheric oxidation of volatile
organic compounds (VOCs) as well as in low-temperature oxidation of hydrocarbon fuels …

Methanol is widely recognized as a carbon-neutral fuel. This work used synchrotron vacuum
ultraviolet photoionization mass spectrometry (SVUV-PIMS) to study the oxidation process of …

The low-temperature oxidation of propanol isomers (n-propanol and iso-propanol) initiated
by ozone addition was carried out in a jet-stirred reactor at an equivalence ratio of 0.5, in a …

In cool flames, autoxidation of organic compounds forms alkyl hydroperoxides and
ketohydroperoxides, and this controls the critical rate of chain branching, but there have …

Peroxy radicals (RO 2) are key reactive intermediates in atmospheric oxidation processes
and yet their chemistry is not fully unraveled. Little is known about their structures and the …

A transient carbon-centered hydroperoxyalkyl intermediate (• QOOH) in the oxidation of
cyclopentane is identified by IR action spectroscopy with time-resolved unimolecular decay …

As a representative aromatic component of practical fuels, understanding the low
temperature chemistry of 1, 2, 4-trimethylbenzene under the reaction environment of fuel …