Conspectus Like singlet carbenes and silylenes, transient electrophilic terminal
phosphinidene complexes enabled highly selective synthetic transformations, but the …

This chapter covers the literature published during 2013 relating to the above area, apart
from a few papers from 2012 in less accessible journals which came to light in Chemical …

P-Trityl substituted Li/Cl phosphinidenoid tungsten (0) complex (OC) 5W {Ph3CP (Li/12-
crown-4) Cl}(3) was prepared via chlorine/lithium exchange in complex (OC) 5W …

High-frequency and-field electron paramagnetic resonance (HFEPR), in its current
configuration (frequencies up to 1THz; fields up to 35T), has been applied to transition metal …

Organophosphorus Chemistry provides a comprehensive annual review of the literature.
Coverage includes phosphines and their chalcogenides, phosphonium salts, low …

Ring expansion of strained small rings provides an efficient method for the synthesis of
various high-value carbocycles and heterocycles. Here we report BF3· Et2O as both an …

This feature article highlights the discovery and development of phosphanoxyl complex
chemistry starting from (neutral) low-coordinate phosphorus radicals and the quest of metal …

Abstract While PV 1, 2‐oxaphosphetanes are well known from the Wittig reaction, their PIII
analogues are still unexplored. Herein, the synthesis and reactions of the first 1, 2 …

The synthesis of PF phosphane metal complexes [(CO) 5M {RP (H) F}] 2a–c (R= CH (SiMe3)
2; a: M= W; b: M= Mo; c: M= Cr) is described using AgBF4 for a Cl/F exchange in P-Cl …

Facile access to [W (CO) 5 (Ph2P‐OTEMP)] is used to initiate a study on the generation,
properties, and reactions of transient phosphanoxyl complexes [MLn (R2PO)], the first …