Octacyanidometallates have been successfully employed in the design of heterometallic
coordination systems offering a spectacular range of desired physical properties with great …

The study of paramagnetic compounds based on 4d and 5d transition metals is an emerging
research topic in the field of molecular magnetism. An essential driving force for the interest …

Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

The binuclear complexes (3d–3d, 3d–3d′, 3d–4f) with compartmental ligands can
efficiently act as tectons in crystal engineering. Various high nuclearity clusters and …

Polymetallic complexes are more and more involved in materials science. The metal ions
exert a functional role, carrying magnetic, optical, or redox properties, and a structural one …

Molecule-based solids represent a rare opportunity to combine, adjust, and interrelate
structural and physical functionalities to develop multifunctional materials. Here we report on …

Complete overview of octacyanidometallate polymetallic assemblies is presented from a
novel viewpoint of the importance of incorporated ligands. The ligands are classified …

This paper reviews the most representative examples of heterometallic complexes
containing three different paramagnetic metal ions, focusing on their magnetic properties …

Nonconventional heptacoordination in combination with efficient magnetic exchange
coupling is shown to yield a 1-D heteronuclear {FeIINbIV} compound with remarkable …

A series of dinuclear [NiIILnIII] Schiff-base complexes (using a Schiff-base dicompartmental
ligand derived from o-vanillin [H2valpn= 1, 3-propanediylbis (2-iminomethylene-6-methoxy …