Nanostructured materials and interfaces for advanced ionic electronic conducting oxides

M Acosta, F Baiutti, A Tarancón… - Advanced Materials …, 2019 - Wiley Online Library
Mixed ionic electronic conductors (MIEC) are pivotal materials in a number of
electrochemical devices that are relevant for clean energy technologies and industrial …

In situ optical absorption studies of point defect kinetics and thermodynamics in oxide thin films

HB Buckner, NH Perry - Advanced Materials Interfaces, 2019 - Wiley Online Library
The authors review the use of in situ optical absorption to probe point defect equilibria and
kinetics in oxides, with particular attention to thin films and high‐temperature measurements …

Transforming an Ionic Conductor into an Electronic Conductor via Crystallization: In Situ Evolution of Transference Numbers and Structure in (La,Sr)(Ga,Fe)O3‐x …

HB Buckner, J Simpson‐Gomez… - Advanced Functional …, 2024 - Wiley Online Library
Mixed‐conducting perovskites are workhorse electrochemically active materials, but typical
high‐temperature processing compromises their catalytic activity and chemo‐mechanical …

Segregation induced self‐assembly of highly active perovskite for rapid oxygen reduction reaction

Y Li, W Zhang, T Wu, Y Zheng, J Chen… - Advanced Energy …, 2018 - Wiley Online Library
The development of high‐performance electrochemical energy storage and conversion
technologies hinges largely on the creation of highly efficient and durable electrode …

UV-Driven Oxygen Surface Exchange and Stoichiometry Changes in a Thin-Film, Nondilute Mixed Ionic Electronic Conductor, Sr(Ti,Fe)O3-d

EJ Skiba, HB Buckner, C Lee, G McKnight… - Journal of the …, 2024 - ACS Publications
Enabling light-controlled ionic devices requires insight into photoionic responses in
technologically relevant materials. Mixed-conducting perovskites containing nondilute Fe─ …

Oxygen surface exchange kinetics measurement by simultaneous optical transmission relaxation and impedance spectroscopy: Sr(Ti,Fe)O3-x thin film case study

NH Perry, JJ Kim, HL Tuller - Science and Technology of advanced …, 2018 - Taylor & Francis
We compare approaches to measure oxygen surface exchange kinetics, by simultaneous
optical transmission relaxation (OTR) and AC-impedance spectroscopy (AC-IS), on the …

Origins and Control of Optical Absorption in a Nondilute Oxide Solid Solution: Sr(Ti,Fe)O3–x Perovskite Case Study

NH Perry, N Kim, E Ertekin, HL Tuller - Chemistry of Materials, 2019 - ACS Publications
Understanding and rationally tailoring defect-mediated optical absorption of nondilute oxide
solid solutions represents a complex challenge. In this work, we investigate compositions in …

Simultaneous Electrical, Electrochemical, and Optical Relaxation Measurements of Oxygen Surface Exchange Coefficients: Sr(Ti,Fe)O3−d Film Crystallization Case …

EJ Skiba, T Chen, NH Perry - ACS Applied Materials & Interfaces, 2020 - ACS Publications
The oxygen surface exchange coefficient (k) dictates the efficiency and response time of
many mixed conductors, so its accurate, continuous measurement in realistic conditions …

High-Temperature 2D Optical Relaxation Visualizes Enhanced Oxygen Exchange Kinetics at Metal-Mixed Conducting Oxide Interfaces

EJ Skiba, NH Perry - ACS Applied Materials & Interfaces, 2022 - ACS Publications
Solid-state heterointerfaces are of interest for emergent local behavior that is distinct from
either bulk parent compound. One technologically relevant example is the case of mixed …

Surface Space‐Charge Potential and Oxygen Surface Exchange Coefficient of SrTiO3: The Effect of Surface Orientation

J Kler, JM Börgers, RA De Souza - Advanced Materials …, 2023 - Wiley Online Library
Abstract 18O2/16O2 exchange experiments on terminated (100),(110), and (111) oriented
samples of single‐crystal SrTiO3 are used to study the effect of surface orientation on the …