The area of transition‐metal‐catalyzed direct arylation through cleavage of C H bonds has
undergone rapid development in recent years, and is becoming an increasingly viable …

Arylraryl bond formation is one of the most important tools of modern organic synthesis.
These bonds are very often found in natural products such as alkaloids as well as in …

The biaryl structural motif is a predominant feature in many pharmaceutically relevant and
biologically active compounds. As a result, for over a century1 organic chemists have sought …

The past half century has witnessed enormous growth in transition-metal organometallic
chemistry, both as a scientific discipline and as a subject for research and applications in …

Euler, a Swiss mathematician, demonstrated that a planar sheet of hexagons can be
converted to a curved surface by inclusion of pentagons, 12 being a “magic” number for the …

Das Gebiet der übergangsmetallkatalysierten direkten Arylierung unter C‐H‐Bindungsbruch
hat in den letzten Jahren eine rasante Entwicklung erfahren, was dazu führte, dass sich …

Geodesic polyarenes constitute a rapidly growing family of polycyclic aromatic hydrocarbons
(PAHs) that resemble the geodesic domes of the great 20th century American architect …

Recently, the use of the palladium-catalyzed inter-and/or intra-molecular C–H bond
arylations in the building of various π-extended (hetero) aromatic structures has emerged as …

An efficient entry process for the synthesis of corannulene has been demonstrated on
kilogram scale. Compared to the discovery and gram-scale syntheses, the amounts of …

The synthesis and structural analysis of a quintuple [6] helicene with a corannulene core is
reported. The compound was synthesized from corannulene in three steps including a five …