Recent advances in carbon dioxide hydrogenation to methanol via heterogeneous catalysis

X Jiang, X Nie, X Guo, C Song, JG Chen - Chemical reviews, 2020 - ACS Publications
The utilization of fossil fuels has enabled an unprecedented era of prosperity and
advancement of well-being for human society. However, the associated increase in …

Achievements and challenges of copper‐based single‐atom catalysts for the reduction of carbon dioxide to C2+ products

T Tang, Z Wang, J Guan - Exploration, 2023 - Wiley Online Library
Copper is the only metal that can convert CO2 into C2 and C2+ in electrocatalytic carbon
dioxide reduction (CO2RR). However, the Faraday efficiency of CO2 conversion to C2 and …

Asymmetric Sites on the ZnZrOx Catalyst for Promoting Formate Formation and Transformation in CO2 Hydrogenation

Z Feng, C Tang, P Zhang, K Li, G Li… - Journal of the …, 2023 - ACS Publications
The role of formate species for CO2 hydrogenation is still under debate. Although formate
has been frequently observed and commonly proposed as the possible intermediate, there …

Highly active Pt/In2O3-ZrO2 catalyst for CO2 hydrogenation to methanol with enhanced CO tolerance: The effects of ZrO2

K Sun, C Shen, R Zou, C Liu - Applied Catalysis B: Environmental, 2023 - Elsevier
The supported Pt catalyst is normally not active for CO 2 hydrogenation to methanol at the
presence of CO. Herein, ZrO 2 is added into Pt/In 2 O 3 for CO 2 hydrogenation to methanol …

Exploring the ternary interactions in Cu–ZnO–ZrO2 catalysts for efficient CO2 hydrogenation to methanol

Y Wang, S Kattel, W Gao, K Li, P Liu, JG Chen… - Nature …, 2019 - nature.com
The synergistic interaction among different components in complex catalysts is one of the
crucial factors in determining catalytic performance. Here we report the interactions among …

CO2 Hydrogenation to Methanol over ZrO2-Containing Catalysts: Insights into ZrO2 Induced Synergy

K Li, JG Chen - ACS catalysis, 2019 - ACS Publications
Catalytic hydrogenation of CO2 with renewable H2 to methanol represents a promising
pathway for reducing anthropogenic CO2 emissions. Catalysts play a key role in enhancing …

Ni–In Synergy in CO2 Hydrogenation to Methanol

J Zhu, F Cannizzaro, L Liu, H Zhang, N Kosinov… - ACS …, 2021 - ACS Publications
Indium oxide (In2O3) is a promising catalyst for selective CH3OH synthesis from CO2 but
displays insufficient activity at low reaction temperatures. By screening a range of promoters …

Plasma-catalytic CO2 hydrogenation to methanol over CuO-MgO/Beta catalyst with high selectivity

Q Chen, S Meng, R Liu, X Zhai, X Wang, L Wang… - Applied Catalysis B …, 2024 - Elsevier
Herein, we report a CuO-MgO/Beta catalyst, which exhibits 72.0% methanol selectivity with
8.5% CO 2 conversion in plasma-catalytic CO 2 hydrogenation at ambient conditions (30° C …

Isolated Zr Surface Sites on Silica Promote Hydrogenation of CO2 to CH3OH in Supported Cu Catalysts

E Lam, K Larmier, P Wolf, S Tada… - Journal of the …, 2018 - ACS Publications
Copper nanoparticles supported on zirconia (Cu/ZrO2) or related supported oxides
(Cu/ZrO2/SiO2) show promising activity and selectivity for the hydrogenation of CO2 to …

Green hydrogen coupling with CO2 utilization of coal-to-methanol for high methanol productivity and low CO2 emission

W Dongliang, M Wenliang, Z Huairong, L Guixian… - Energy, 2021 - Elsevier
The conventional coal-to-methanol (CTM) process suffers from large CO 2 emission. The
additional hydrogen supplement to the CTM process can effectively improve the carbon …