Conspectus Over recent decades, N-sulfonylhydrazones have attracted significant attention
in academic and industrial contexts owing to their ease of preparation, versatile reactivity …

Conspectus Bridged and fused rings are commonly found in biologically important
molecules. Current tactics to construct these ring systems are primarily based on stepwise …

The exploration of the complex chemical diversity of bicyclo [n. 1.1] alkanes and their use as
benzene bioisosteres has garnered significant attention over the past two decades …

Chiral seven-membered ring systems such as seven-membered carbocycles and
heterocycles are widely found in natural products and pharmaceuticals. Therefore, the …

Palladium‐catalyzed decarboxylative cycloadditions have emerged as highly effective
methods for constructing structurally diverse carbo‐and heterocycles because of the …

Abstract A photocatalytic self‐(3+ 2) cycloaddition of vinyldiazo compounds is described,
which provides cyclopentene derivatives with conservation of one diazo functional group …

Abstract The palladium‐catalyzed asymmetric [4+ 3] cyclization of trimethylenemethane
donors with benzofuran‐derived azadienes furnishes chiral benzofuro [3, 2‐b] azepine …

We describe herein a highly diastereo‐and enantioselective [4+ 3]‐cycloannulation of ortho‐
quinone methides and carbonyl ylides to furnish functionalized oxa‐bridged …

New discoveries require a fundamental revision of the view on the mechanism of the
32CAreaction (according to the older nomenclature defined as 1, 3-dipolar cycloaddition …

Carbocycles are a key and widely present structural motif in organic compounds. The
construction of structurally intriguing carbocycles, such as highly-strained fused rings …