Divalent metallocenes of the lanthanides–a guideline to properties and reactivity

S Schäfer, S Kaufmann, ES Rösch… - Chemical Society …, 2023 - pubs.rsc.org
Since the discovery in the early 1980s, the soluble divalent metallocenes of lanthanides
have become a steadily growing field in organometallic chemistry. The predominant part of …

Metallosupramolecular polyelectrolytes self-assembled from various pyridine ring-substituted bisterpyridines and metal ions: photophysical, electrochemical, and …

FS Han, M Higuchi, DG Kurth - Journal of the American Chemical …, 2008 - ACS Publications
This work presents several metallosupramolecular coordination polyelectrolytes (MEPEs)
self-assembled from rigid, π-conjugated, pyridine ring functionalized bisterpyridines and …

Exchange coupling and magnetic blocking in dilanthanide complexes bridged by the multi-electron redox-active ligand 2, 3, 5, 6-tetra (2-pyridyl) pyrazine

S Demir, M Nippe, MI Gonzalez, JR Long - Chemical Science, 2014 - pubs.rsc.org
The syntheses and magnetic properties of six new compounds featuring the radical-bridged
dilanthanide complexes [(Cp* 2Ln) 2 (μ-tppz˙)]+(Ln= Gd, 1; Tb, 2; Dy, 3; tppz= 2, 3, 5, 6-tetra …

Inverse coordination. Organic nitrogen heterocycles as coordination centers. A survey of molecular topologies and systematization. Part 2. Six-membered rings

I Haiduc - Journal of Coordination Chemistry, 2019 - Taylor & Francis
The review is a follow-up of a previous article (I. Haiduc, J. Coord. Chem.(2019). DOI:
10.1080/00958972.2019. 1641702), which introduced structures with five-membered …

Synthesis, structure, and reactivity of a thorium metallocene containing a 2, 2′-bipyridyl ligand

W Ren, G Zi, MD Walter - Organometallics, 2012 - ACS Publications
The reduction of [η5-1, 2, 4-(Me3C) 3C5H2] 2ThCl2 (1) with potassium graphite in the
presence of 2, 2′-bipyridine gives the purple thorium bipy metallocene [η5-1, 2, 4-(Me3C) …

A bipyridyl thorium metallocene: synthesis, structure and reactivity

W Ren, H Song, G Zi, MD Walter - Dalton Transactions, 2012 - pubs.rsc.org
The synthesis, structure and reactivity of a new bipy thorium metallocene have been studied.
The reduction of the thorium chloride metallocene [η5-1, 3-(Me3C) 2C5H3] 2ThCl2 (1) with …

Stoichiometrically Controlled Assembly of Lanthanide Molecular Complexes of the Heteroditopic Divergent Ligand 4′-(4-Pyridyl)-2,2′:6′,2″-terpyridine N-Oxide …

L Fioravanti, L Bellucci, L Armelao, G Bottaro… - Inorganic …, 2021 - ACS Publications
Mononuclear rare-earth tris-β-diketonato complexes RE (tta) 3dme [RE= Y (1), La (2), Dy (3),
or Eu (4); Htta= 2-thenoylacetone; dme= 1, 2-dimethoxyethane] react cleanly at room …

Spectroscopic Investigation of the Ultrafast Photoinduced Dynamics in π‐Conjugated Terpyridines

R Siebert, D Akimov, M Schmitt, A Winter… - …, 2009 - Wiley Online Library
Ultrafast light‐induced processes in a series of π‐conjugated mono‐, bis‐, tris‐and tetrakis
(terpyridine) derivatives are investigated by femtosecond time‐resolved spectroscopy. Non …

Deca-arylsamarocene: An unusually inert Sm (II) sandwich complex

NJC van Velzen, S Harder - Organometallics, 2018 - ACS Publications
Samarocene sandwich complexes with superbulky penta-arylcyclopentadienyl ligands have
been prepared and were structurally characterized:[(4-EtC6H4) 5C5] 2Sm (1) and [(4-i …

Coordination of 1, 4-diazabutadiene ligands to decamethylytterbocene: additional examples of spin coupling in ytterbocene complexes

MD Walter, DJ Berg, RA Andersen - Organometallics, 2007 - ACS Publications
The paramagnetic 1: 1 coordination complexes of (C5Me5) 2Yb with a series of
diazabutadiene ligands, RN C (R ') C (R ') NR, where R= CMe3, CHMe2, adamantyl, p-tolyl …