Transition-metal-catalyzed, coordination-assisted C (sp3)–H functionalization has
revolutionized synthetic planning over the past few decades as the use of these directing …

Organoborons have emerged as versatile building blocks in organic synthesis to achieve
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …

Cross-electrophile coupling (XEC) reactions of aryl and alkyl electrophiles are appealing but
limited to specific substrate classes. Here, we report electroreductive XEC of previously …

Employing phenols and phenol derivatives as electrophiles for cross-coupling reactions has
numerous advantages over commonly used aryl halides in terms of environmental …

The story of C− C bond formation includes several reactions, and surely Suzuki‐Miyaura is
among the most outstanding ones. Herein, a brief historical overview of insights regarding …

Transition-metal-catalyzed cross-coupling reactions have been well-established as
indispensable tools in modern organic synthesis. One of the major research goals in cross …

Zinc and manganese are widely used as reductants in synthetic methods, such as nickel-
catalysed cross-electrophile coupling (XEC) reactions, but their redox potentials are …

Conspectus Nickel complexes exhibit distinct properties from other group 10 metals,
including a small nuclear radius, high paring energy, low electronegativity, and low redox …

Driven by the inherent synthetic potential of CO2 as an abundant, inexpensive and
renewable C1 chemical feedstock, the recent years have witnessed renewed interest in …

Cross-coupling reactions, which were discovered almost 50 years ago, are widely used in
both industry and academia. Even though cross-coupling reactions now represent mature …