Although carbon is the central element of organic chemistry, oxygen is the central element of
stereoelectronic control in organic chemistry. Generally, a molecule with a C–O bond has …

Conspectus The encapsulation of ions into macro (bi) cyclic hosts lies at the core of
supramolecular chemistry. While chemically inert hosts such as crown ethers (synthesis) …

The dynamic covalent chemistry (DCvC) of the Si− O bond holds unique opportunities, but
has rarely been employed to assemble discrete molecular architectures. This may be due to …

Shapeshifting molecules exhibit rapid constitutional dynamics while remaining stable,
isolable molecules, making them promising artificial scaffolds from which to explore complex …

For a variety of purposes, it is of interest to embed metals in cagelike trans-spanning di
(triaryl) phosphine ligands. Toward this end, a combination of P (p-C6H4O (CH2) m CH═ …

Abstract Three shape‐persistent [4+ 4] imine cages with truncated tetrahedral geometry with
different window sizes were studied as hosts for the encapsulation of tetra‐n …

Understanding dynamic systems is a crucial step toward the design of complex matter. Here,
we aim to study the behavior of Constitutional Dynamic Networks (CDNs) in conditions of …

We report on triethylene glycol‐based orthoformate cryptands, which adapt their bridgehead
configurations in response to metal templates and intramolecular hydrogen bonding in a …

Adaptive chemistry allows transformation and selection within molecular networks, and
adaptive systems composed of different types of dynamic covalent reactions (DCRs) are …

Herein we demonstrate that the rapid 'shapeshifting'constitutional isomerization of a
substituted bullvalene is influenced by the E-to-Z configurational isomerization of a remote …