Ethanol dehydrogenation to acetaldehyde with mesoporous Cu-SiO2 catalysts prepared by aerosol-assisted sol–gel

G Pampararo, G Garbarino, P Riani, V Vykoukal… - Chemical Engineering …, 2023 - Elsevier
Copper based catalysts are central for carrying dehydrogenation reactions. However, these
materials are prone to deactivation by sintering and coke deposition. Irreversible sintering …

Suppressing on-stream deactivation of CuSiO 2 catalysts in the dehydrogenation of bioethanol to acetaldehyde

G Pampararo, Z Hlavenková, A Styskalik… - Catalysis Science & …, 2024 - pubs.rsc.org
Bioethanol upgrading to valuable platform molecules is a cornerstone of the emerging
“integrated biorefinery” concept. Although active catalysts have already been developed for …

Spectroscopic studies of surface copper spinels. Influence of pretreatments on chemical state of copper

A Sepulveda, C Marquez… - Surface and …, 1993 - Wiley Online Library
The nature of copper species of a series of alumina‐supported copper samples was
investigated by the kinetics of reduction, x‐ray photoelectron spectroscopy, temperature …

Influence of nitrogen dioxide on the selective reduction of NOx with a catalyst of copper and nickel oxides

J Blanco, P Avila, JLG Fierro - Applied Catalysis A: General, 1993 - Elsevier
The selective reduction of NO x, with ammonia on alumina-supported copper catalysts is
shown to be effective when O 2 or NO 2 are present in the feed. Under steady state …

Decomposition of NO on Cu-loaded zeolites

A Sepulveda-Escribano, C Marquez-Alvarez… - Catalysis today, 1993 - Elsevier
Two copper ion-exchanged zeolites, Cu/NaY and Cu/NaZSM-5 have been studied by
several techniques (TPR, TPD of NO, IR spectroscopy of adsorbed NO and XPS) and their …

Characterization of corrosion products on chalcographic copper plates after 200 years' exposure to indoor atmospheres

E Otero, JM Bastidas Rull, W Lopez, JL García Fierro - 1994 - digital.csic.es
This work studies the characterization of corrosion products formed on six eighteenth
century chalcographic copper plates preserved in the National Chalcography Collection in …

Methanol dehydrogenation in the liquid phase with Cu-based solid catalysts

T Yamakawa, T Ohnishi, S Shinoda - Catalysis letters, 1994 - Springer
Studies of methanol dehydrogenation in the liquid phase with Cu-based solid catalysts have
shown (i) the product (methylal) is totally different from that in the gas-solid phase reaction …

[PDF][PDF] Improving On-stream Stability of Cu-SiO2 Catalysts in the Dehydrogenation of Bioethanol to Acetaldehyde

G Pampararo, Z Hlavenkova, A Styskalik, DP Debecker - dial.uclouvain.be
Bioethanol upgrading to valuable platform molecules, is a cornerstone of the emerging
“integrated biorefinery” concept. Although active catalysts have already been developed for …

[PDF][PDF] Ethanol dehydrogenation to acetaldehyde with mesoporous Cu-SiO2 catalysts prepared by 2 aerosol-assisted sol-gel 3

G Pampararo, G Garbarino, P Riani, V Vykoukal… - dial.uclouvain.be
Copper based catalysts are central for carrying dehydrogenation reactions. However, these
23 materials are prone to deactivation by sintering and coke deposition. Irreversible …

X-ray Photoelectron Spectroscopy of Cu-ZSM-5 Zeolite

LP Haack, M Shelef - 1994 - ACS Publications
The determination of the oxidation state of copper in Cu-exchanged ZSM-5 is important for
understanding its role in the mechanism of decomposition and selective reduction of NO …