Much effort has been devoted to developing new methods using Ni catalysts for the cross-
coupling reaction of alkyl electrophiles with organometallic reagents, and significant …

In typical catalytic organic transformations, transition metals in catalytically active complexes
are present in their most stable valence states, such as palladium (0) and (II). However …

An electron rich Ni (I)–Ni (I) bond supported by a doubly reduced naphthyridine–diimine
(NDI) ligand reacts rapidly and reversibly with Ph2SiH2 and Et2SiH2 to form stable adducts …

Redox-active nitrogen donor ligands have exhibited broad utility in stabilizing transition
metal complexes in unusual formal oxidation states and enabling multielectron redox …

Copper(I) Alkyne and Alkynide Complexes | Organometallics ACS ACS Publications C&EN CAS
Find my institution Log In Organometallics ACS Publications. Most Trusted. Most Cited. Most …

High yield syntheses of (iPr3P) 2NiX (3a–c),(where X= Cl, Br, I) were established by
comproportionation of (iPr3P) 2NiX2 (1a–c) with (iPr3P) 2Ni (η2-C2H4)(2). Reaction of 1a …

Nickel catalysts represent a low cost and environmentally friendly alternative to palladium-
based catalytic systems for Suzuki–Miyaura cross-coupling (SMC) reactions. However …

The bimetallic formamidinate complexes Ln (Form)(AlMe4) 2 (Ln= Y, Form (ArNCHNAr)=
EtForm (Ar= 2, 6-Et2C6H3), MesForm (Ar= 2, 4, 6-Me3C6H2), DippForm (Ar= 2, 6-i …

The diamagnetic cobalt (III) dimethyl complex, cis, mer-(PMe3) 3Co (CH3) 2I, was found to
promote selective C–C bond formation, affording ethane and triplet (PMe3) 3CoI. The …

The previously reported mononuclear d9 complex (i Pr3P) 2NiCl (1) provides a convenient
entry into a series of dinickel complexes with syn-facial bridging ligands …