Conspectus Nickel complexes exhibit distinct properties from other group 10 metals,
including a small nuclear radius, high paring energy, low electronegativity, and low redox …

Organometallic catalysts have played a key role in accomplishing numerous synthetically
valuable organic transformations that are either otherwise not possible or inefficient. The use …

The recent success of nickel catalysts in stereoconvergent cross-coupling and cross-
electrophile coupling reactions partly stems from the ability of monovalent nickel species to …

Ni (I)-mediated single-electron oxidative activation of alkyl halides has been extensively
proposed as a key step in Ni-catalyzed cross-coupling reactions to generate radical …

The myriad nickel-catalyzed cross-coupling reactions rely on the formation of an
organonickel intermediate, but limitations in forming monoalkylnickel species have limited …

The activation and selective transformation of virtually inexhaustible or easy-to-generate
chemicals like N2, O2, CO2, CO, H2, or methane gas to value-added products is a lively …

Conspectus Nickel pincer systems have recently attracted much attention for applications in
various organometallic reactions and catalysis involving small molecule activation. Their …

Acetyl coenzyme A synthase (ACS) catalyzes the formation and deconstruction of the key
biological metabolite, acetyl coenzyme A (acetyl-CoA). The active site of ACS features a …

In this work, Ni (I) aryl species that are directly relevant to cross-coupling have been
synthesized. Transmetalation of (dppf) NiIX (dppf= 1, 1′-bis (diphenylphosphino) …

Conspectus Carbon dioxide conversion mediated by transition metal complexes continues
to attract much attention because of its future potential utilization as a nontoxic and …