Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties

Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …

Thiolate‐protected metal nanoclusters: recent development in synthesis, understanding of reaction, and application in energy and environmental field

T Kawawaki, A Ebina, Y Hosokawa, S Ozaki, D Suzuki… - Small, 2021 - Wiley Online Library
Metal nanoclusters (NCs), which are composed of about 250 or fewer metal atoms, possess
great potential as novel functional materials. Fundamental research on metal NCs gradually …

Atomically precise thiolate‐protected gold nanoclusters: Current status of designability of the structure and physicochemical properties

S Hossain, D Hirayama, A Ikeda, M Ishimi… - …, 2023 - Wiley Online Library
Thiolate (SR)‐protected gold nanoclusters (Aun (SR) m NCs) are a rare type of material
capable of simultaneously exhibiting multiple physicochemical properties well‐suited to …

An overview on the current understanding of the photophysical properties of metal nanoclusters and their potential applications

S Maity, D Bain, A Patra - Nanoscale, 2019 - pubs.rsc.org
Photophysics of atomically precise metal nanoclusters (MNCs) is an emerging area of
research due to their potential applications in optoelectronics, photovoltaics, sensing, bio …

The factors dictating properties of atomically precise metal nanocluster electrocatalysts

H Yan, H Xiang, J Liu, R Cheng, Y Ye, Y Han, C Yao - Small, 2022 - Wiley Online Library
Metal nanoparticles occupy an important position in electrocatalysis. Unfortunately, by using
conventional synthetic methodology, it is a great challenge to realize the monodisperse …

Toward the creation of high-performance heterogeneous catalysts by controlled ligand desorption from atomically precise metal nanoclusters

T Kawawaki, Y Kataoka, M Hirata, Y Iwamatsu… - Nanoscale …, 2021 - pubs.rsc.org
Ligand-protected metal nanoclusters controlled by atomic accuracy (ie atomically precise
metal NCs) have recently attracted considerable attention as active sites in heterogeneous …

Atomically precise alloy nanoclusters

T Kawawaki, Y Imai, D Suzuki, S Kato… - … A European Journal, 2020 - Wiley Online Library
Metal nanoclusters (NCs) have a particle size of about one nanometer, which makes them
the smallest unit that can give a function to a substance. In addition, metal NCs possess …

Controlling aggregation-induced emission in bimetallic gold–copper nanoclusters via surface motif engineering

S Chakraborty, D Bain, S Maity, S Kolay… - The Journal of Physical …, 2022 - ACS Publications
Aggregation-induced emission (AIE) has been significantly explored to enhance
luminescence properties. Here, we synthesized bimetallic AuCu nanoclusters (NCs) and …

In situ two-phase ligand exchange: a new method for the synthesis of alloy nanoclusters with precise atomic structures

S Yang, J Chai, Y Song, J Fan, T Chen… - Journal of the …, 2017 - ACS Publications
A new method termed “in situ two-phase ligand exchange” was developed to obtain alloy
nanoclusters. With this approach, a series of alloy nanoclusters were obtained for the first …

Evolution of Excited-State Dynamics in Periodic Au28, Au36, Au44, and Au52 Nanoclusters

M Zhou, C Zeng, MY Sfeir, M Cotlet, K Iida… - The Journal of …, 2017 - ACS Publications
Understanding the correlation between the atomic structure and optical properties of gold
nanoclusters is essential for exploration of their functionalities and applications involving …