Ligand‐Enabled Gold‐Catalyzed Cyanation of Organohalides
Herein, we disclose the first report on gold‐catalyzed C (sp2)‐CN cross‐coupling reaction
by employing a ligand‐enabled Au (I)/Au (III) redox catalysis. This transformation utilizes …
by employing a ligand‐enabled Au (I)/Au (III) redox catalysis. This transformation utilizes …
Organometallic Oxidative Addition Complexes for S-Arylation of Free Cysteines
HR Montgomery, AM Spokoyny… - Bioconjugate …, 2024 - ACS Publications
Development of bioconjugation strategies to efficiently modify biomolecules is of key
importance for fundamental and translational scientific studies. Cysteine S-arylation is an …
importance for fundamental and translational scientific studies. Cysteine S-arylation is an …
Photosensitized Reductive Elimination of Gold (III) to Enable Esterification of Aryl Iodides with Carboxylic Acids
J Wu, W Du, L Zhang, G Li, R Yang, Z Xia - JACS Au, 2024 - ACS Publications
Compared to the well-established transition metal-catalyzed cross-coupling reactions, Au
(I)/Au (III)-catalyzed cross-coupling reactions have lagged behind. Despite some …
(I)/Au (III)-catalyzed cross-coupling reactions have lagged behind. Despite some …
Gold-catalyzed fluorination of alkynes/allenes: mechanistic explanations and reaction scope
DS Roy, YBS Tanwer, SR Patra, S Kumar… - Organic & …, 2025 - pubs.rsc.org
Since the beginning of this century, there has been a great deal of research on
homogeneous gold-catalyzed alkyne fluorination due to the precious values of fluorinated …
homogeneous gold-catalyzed alkyne fluorination due to the precious values of fluorinated …
In Silico Screening of P, N-Ligands Facilitates Optimization of Au (III)-Mediated S-Arylation
Metal-mediated cysteine S-arylation is an emerging bioconjugation technique due to its high
chemoselectivity, rapid kinetics, and aqueous compatibility. We have previously …
chemoselectivity, rapid kinetics, and aqueous compatibility. We have previously …
Ruthenium Complexes Bearing a Tetradentate Hemilabile Ligand: Synthesis, Structure, Hemilabile Feature, and Catalytic Application to C–H Borylation of …
Y Liao, K Takahashi, N Iwasawa - Organometallics, 2025 - ACS Publications
Ruthenium complexes bearing a rationally designed tetradentate hemilabile ligand have
been developed. The structures of the complexes and the hemilabile feature of the ligand …
been developed. The structures of the complexes and the hemilabile feature of the ligand …
Tuning the Steric and Electronic Properties of Hemilabile NHC ligands for Gold (I/III) Catalyzed Oxyarylation of Ethylene: A Computational Study
G Galdi, C Costabile - Chemistry–A European Journal, 2024 - Wiley Online Library
Abstract Mechanistic studies on 1, 2‐oxyarylation of ethylene promoted by gold catalysts
bearing hemilabile N‐Heterocyclic Carbene (NHC^ X) ligands were conducted by DFT …
bearing hemilabile N‐Heterocyclic Carbene (NHC^ X) ligands were conducted by DFT …