A review of kinetic modeling methodologies for complex processes

LP de Oliveira, D Hudebine… - Oil & Gas Science …, 2016 - ogst.ifpenergiesnouvelles.fr
In this paper, kinetic modeling techniques for complex chemical processes are reviewed.
After a brief historical overview of chemical kinetics, an overview is given of the theoretical …

Diffusion and catalyst efficiency in hierarchical zeolite catalysts

P Peng, XH Gao, ZF Yan, S Mintova - National Science Review, 2020 - academic.oup.com
The preparation of hierarchical zeolites with reduced diffusion limitation and enhanced
catalyst efficiency has become a vital focus in the field of zeolites and porous materials …

Recent progress toward molecular-level kinetic model for complex hydrocarbon conversion processes

Z Chen, X Zhao, J Wu, C Xu, L Zhang - Chemical Engineering Journal, 2024 - Elsevier
The simulation and optimization of complex molecular conversion systems are one of the
primary challenges in the chemical reaction engineering field. Petroleum refining is a …

Hydroisomerization of long-chain paraffins over nano-sized bimetallic Pt–Pd/H-beta catalysts

F Bauer, K Ficht, M Bertmer, WD Einicke… - Catalysis Science & …, 2014 - pubs.rsc.org
The hydroisomerization of long-chain n-paraffins was studied in the temperature range of
205–230° C at pH2= 50 bar using a pilot-scale trickle-bed continuous-flow reactor over …

Multiscale aspects in hydrocracking: from reaction mechanism over catalysts to kinetics and industrial application

JW Thybaut, GB Marin - Advances in catalysis, 2016 - Elsevier
Hydroisomerization and hydrocracking are widely recognized as versatile reactions. They
allow not only converting feeds of various origin and quality into high-value blendstocks but …

A generalized mechanistic kinetic model for the hydroisomerization and hydrocracking of long-chain paraffins

H Kumar, GF Froment - Industrial & engineering chemistry …, 2007 - ACS Publications
A mechanistic kinetic model has been developed for the three-phase hydroisomerization
and hydrocracking of long-chain paraffins in which rate-determining steps are assumed to …

Hydroisomerization and hydrocracking over platinum loaded ZSM-23 catalysts in the presence of sulfur and nitrogen compounds for the dewaxing of diesel fuel

SW Lee, SK Ihm - Fuel, 2014 - Elsevier
Hydroisomerization and hydrocracking of n-hexadecane in the presence of sulfur and
nitrogen compound were investigated over four different platinum loaded ZSM-23 catalysts …

n-Hexadecane hydrocracking single-event microkinetics on Pt/H-beta

BD Vandegehuchte, JW Thybaut, A Martinez… - Applied Catalysis A …, 2012 - Elsevier
The Single-Event MicroKinetic (SEMK) model constructed for gas-phase hydroconversion of
light n-alkanes on large-pore USY zeolites was applied, for the first time, to the …

Kinetic modeling using the single-event methodology: application to the isomerization of light paraffins

K Surla, D Guillaume… - Oil & Gas Science …, 2011 - ogst.ifpenergiesnouvelles.fr
The construction of kinetic models is an important step in the development of refining
processes. Indeed, these models can be used to predict the performances of the process, to …

Design of Optimum Zeolite Pore System for Central Hydrocracking of Long-Chain n-Alkanes based on a Single-Event Microkinetic Model

JW Thybaut, IR Choudhury, JF Denayer, GV Baron… - Topics in …, 2009 - Springer
Abstract Model based catalyst design is an emerging methodology in the development of
new catalytic materials with properties tailored to the needs of specific industrial …