Recent advances in triplet–triplet annihilation upconversion and singlet fission, towards solar energy applications

AJ Carrod, V Gray, K Börjesson - Energy & Environmental Science, 2022 - pubs.rsc.org
Solar energy is an ample renewable energy resource, with photovoltaic (PV) technology
enabling a direct route from light to electricity. Currently, PVs are limited in photon …

Nanoengineering triplet–triplet annihilation upconversion: from materials to real-world applications

T Schloemer, P Narayanan, Q Zhou, E Belliveau… - ACS …, 2023 - ACS Publications
Using light to control matter has captured the imagination of scientists for generations, as
there is an abundance of photons at our disposal. Yet delivering photons beyond the surface …

Triplet–triplet annihilation based near infrared to visible molecular photon upconversion

P Bharmoria, H Bildirir, K Moth-Poulsen - Chemical Society Reviews, 2020 - pubs.rsc.org
Triplet–triplet annihilation based molecular photon upconversion (TTA-UC) is an exciting
research area for a broad range of photonic applications due to its tunable spectral range …

Storing energy with molecular photoisomers

Z Wang, P Erhart, T Li, ZY Zhang, D Sampedro, Z Hu… - Joule, 2021 - cell.com
Some molecular photoisomers can be isomerized to a metastable high-energy state by
exposure to light. These molecules can then be thermally or catalytically converted back to …

Red light-based dual photoredox strategy resembling the Z-scheme of natural photosynthesis

F Glaser, OS Wenger - JACS Au, 2022 - ACS Publications
Photoredox catalysis typically relies on the use of single chromophores, whereas strategies,
in which two different light absorbers are combined, are rare. In photosystems I and II of …

Improved transition metal photosensitizers to drive advances in photocatalysis

D Kim, VQ Dang, TS Teets - Chemical Science, 2024 - pubs.rsc.org
To function effectively in a photocatalytic application, a photosensitizer's light absorption,
excited-state lifetime, and redox potentials, both in the ground state and excited state, are …

Highly effective near-infrared activating triplet–triplet annihilation upconversion for photoredox catalysis

L Huang, W Wu, Y Li, K Huang, L Zeng… - Journal of the …, 2020 - ACS Publications
Organic triplet–triplet annihilation upconversion (TTA-UC) materials have considerable
promise in areas as broad as biology, solar energy harvesting, and photocatalysis …

High triplet energy iridium (III) isocyanoborato complex for photochemical upconversion, photoredox and energy transfer catalysis

L Schmid, F Glaser, R Schaer… - Journal of the American …, 2022 - ACS Publications
Cyclometalated Ir (III) complexes are often chosen as catalysts for challenging photoredox
and triplet–triplet-energy-transfer (TTET) catalyzed reactions, and they are of interest for …

Low power threshold photochemical upconversion using a zirconium (IV) LMCT photosensitizer

M Yang, S Sheykhi, Y Zhang, C Milsmann… - Chemical …, 2021 - pubs.rsc.org
The current investigation demonstrates highly efficient photochemical upconversion (UC)
where a long-lived Zr (IV) ligand-to-metal charge transfer (LMCT) complex serves as a triplet …

Sensitizer-controlled photochemical reactivity via upconversion of red light

F Glaser, OS Wenger - Chemical Science, 2023 - pubs.rsc.org
By combining the energy input from two red photons, chemical reactions that would normally
require blue or ultraviolet irradiation become accessible. Key advantages of this biphotonic …