Cyclic iron tetra N-heterocyclic carbenes: synthesis, properties, reactivity, and catalysis

TP Schlachta, FE Kühn - Chemical Society Reviews, 2023 - pubs.rsc.org
Cyclic iron tetracarbenes are an emerging class of macrocyclic iron N-heterocyclic carbene
(NHC) complexes. They can be considered as an organometallic compound class inspired …

Detection and characterisation of radicals in biological materials using EPR methodology

CL Hawkins, MJ Davies - Biochimica et Biophysica Acta (BBA)-General …, 2014 - Elsevier
Background Electron paramagnetic resonance (EPR) spectroscopy (also known as electron
spin resonance, ESR, spectroscopy) is widely considered to be the “gold standard” for the …

Synergy of Pd atoms and oxygen vacancies on In2O3 for methane conversion under visible light

L Luo, L Fu, H Liu, Y Xu, J Xing, CR Chang… - Nature …, 2022 - nature.com
Methane (CH4) oxidation to high value chemicals under mild conditions through
photocatalysis is a sustainable and appealing pathway, nevertheless confronting the critical …

Triazine–porphyrin-based hyperconjugated covalent organic framework for high-performance photocatalysis

X Liu, R Qi, S Li, W Liu, Y Yu, J Wang… - Journal of the …, 2022 - ACS Publications
Covalent organic frameworks (COFs) with porphyrins as structural units are a new kind of
porous organic polymers, which have a regular and ordered structure, abundant porosity …

Nearly 100% selective and visible-light-driven methane conversion to formaldehyde via. single-atom Cu and Wδ+

L Luo, X Han, K Wang, Y Xu, L Xiong, J Ma… - Nature …, 2023 - nature.com
Direct solar-driven methane (CH4) reforming is highly desirable but challenging, particularly
to achieve a value-added product with high selectivity. Here, we identify a synergistic …

A Surface Se‐Substituted LiCo[O2−δSeδ] Cathode with Ultrastable High‐Voltage Cycling in Pouch Full‐Cells

Z Zhu, H Wang, Y Li, R Gao, X Xiao, Q Yu… - Advanced …, 2020 - Wiley Online Library
Abstract Cycling LiCoO2 to above 4.5 V for higher capacity is enticing; however, hybrid O
anion‐and Co cation‐redox (HACR) at high voltages facilitates intrinsic Oα−(α< 2) migration …

High-performance photocatalytic decomposition of PFOA by BiOX/TiO2 heterojunctions: Self-induced inner electric fields and band alignment

X Liu, X Duan, T Bao, D Hao, Z Chen, W Wei… - Journal of Hazardous …, 2022 - Elsevier
Abstract BiOX (X= Cl, Br and I) and BiOX/TiO 2 photocatalysts were prepared by a facile
hydrothermal approach. The BiOX/TiO 2 heterojunctions demonstrated significantly …

Stimuli-modulated metal oxidation states in photochromic MOFs

CR Martin, KC Park, GA Leith, J Yu… - Journal of the …, 2022 - ACS Publications
Tuning metal oxidation states in metal–organic framework (MOF) nodes by switching
between two discrete linker photoisomers via an external stimulus was probed for the first …

Highly-crystalline triazine-PDI polymer with an enhanced built-in electric field for full-spectrum photocatalytic phenol mineralization

H Zhang, X Chen, Z Zhang, K Yu, W Zhu… - Applied Catalysis B …, 2021 - Elsevier
Herein, a conjugated triazine-perylene diimide (triazine-PDI) polymer photocatalyst is
prepared, and its full-spectrum photo-oxidative activity is evaluated. Enhanced dipole …

Reactive oxygen species generation by copper (II) oxide nanoparticles determined by DNA damage assays and EPR spectroscopy

C Angelé-Martínez, KVT Nguyen, FS Ameer… - …, 2017 - Taylor & Francis
Copper (II) oxide nanoparticles (NPCuO) have many industrial applications, but are highly
cytotoxic because they generate reactive oxygen species (ROS). It is unknown whether the …