Chiral phosphorus ligands play a crucial role in asymmetric catalysis for the efficient
synthesis of useful optically active compounds. They are largely categorized into two …

Phosphorus compounds bearing chirality on the P-center are usually qualified as P-
chirogenic or P-stereogenic. This chemical class concerns natural products, agrochemistry …

Since the development of BisP* ligand by Imamoto, P-stereogenic phosphines bearing a
bulky tert-butyl group and a smaller alkyl group have demonstrated extraordinary proficiency …

The practical synthesis of P-stereogenic tertiary phosphines, which have wide applications
in asymmetric catalysis, materials, and pharmaceutical chemistry, represents a significant …

P‐stereogenic tert‐and sec‐phosphines have wide applications in asymmetric catalysis,
materials, and pharmaceutical chemistry, however, their practical synthesis still constitutes a …

A general and mild nickel‐catalyzed enantioselective C (sp2)− P cross‐coupling for
synthesizing P‐stereogenic phosphine oxides has been developed. The asymmetric …

A nickel-catalyzed asymmetric allylation of secondary phosphine oxides (SPO) for the
synthesis of tertiary phosphine oxides (TPO) was realized with high enantioselectivity. The …

The phosphorus stereocentre, present in a diversity of compounds ranging from
phosphonates to phosphines, plays a crucial role in various fields, in particular catalysis …

The synthesis of phosphorus molecules presenting a chiral center on the P‐atom, also
known as P‐stereogenic compounds, has long attracted the curiosity of the scientific …

Secondary phosphine oxides present tautomeric equilibrium between the pentavalent oxide
form (SPO) and the trivalent phosphinous acid (PA). This dichotomy is the origin of the rich …