Visible light photocatalysis in the late-stage functionalization of pharmaceutically relevant compounds

R Cannalire, S Pelliccia, L Sancineto… - Chemical Society …, 2021 - pubs.rsc.org
The late stage functionalization (LSF) of complex biorelevant compounds is a powerful tool
to speed up the identification of structure–activity relationships (SARs) and to optimize …

Rare‐earth incorporated alloy catalysts: Synthesis, properties, and applications

S Zhang, SE Saji, Z Yin, H Zhang, Y Du… - Advanced …, 2021 - Wiley Online Library
To improve the performance of metallic catalysts, alloying provides an efficient methodology
to design state‐of‐the‐art materials. As emerging functional materials, rare‐earth metal …

Synthetic methods driven by the photoactivity of electron donor–acceptor complexes

GEM Crisenza, D Mazzarella… - Journal of the American …, 2020 - ACS Publications
The association of an electron-rich substrate with an electron-accepting molecule can
generate a new molecular aggregate in the ground state, called an electron donor–acceptor …

[HTML][HTML] Synthetic reactions driven by electron-donor–acceptor (EDA) complexes

Z Yang, Y Liu, K Cao, X Zhang… - Beilstein Journal of …, 2021 - beilstein-journals.org
The reversible, weak ground-state aggregate formed by dipole–dipole interactions between
an electron donor and an electron acceptor is referred to as an electron-donor–acceptor …

Recent Advances in the Construction of Spiro Compounds via Radical Dearomatization

WC Yang, MM Zhang, JG Feng - Advanced Synthesis & …, 2020 - Wiley Online Library
The field in dearomatization of aromatic compounds for the construction of spirocycle
compounds has been developed rapidly over the last two decades and it provides …

Electrochemical Trifluoromethylthiolation and Spirocyclization of Alkynes with AgSCF3: Access to SCF3-Containing Spiro[5,5]trienones

WC Yang, MM Zhang, Y Sun, CY Chen, L Wang - Organic Letters, 2021 - ACS Publications
A novel and efficient strategy for trifluoromethylthiolation and dearomatization of activated
alkynes with stable and readily available AgSCF3 has been developed. Reported herein is …

Progress in Photoinduced Radical Reactions using Electron Donor‐Acceptor Complexes

L Zheng, L Cai, K Tao, Z Xie, YL Lai… - Asian Journal of …, 2021 - Wiley Online Library
Photocatalyzed organic synthesis transformation is a remarkable green synthetic strategy
because of the advantages of operational simplicity, high chemoselectivities, cheap, and …

Recent Advances in Visible‐Light‐Driven C− S Bond Formation

J Feng, Y Zhang, X Wang, J Liu… - Advanced Synthesis …, 2023 - Wiley Online Library
Due their multifaced applications, the access to organosulfur derivatives in an efficient and
economical way is a challenge in organic synthesis. In this context photochemistry and …

Functionalization of pyridinium derivatives with 1, 4-dihydropyridines enabled by photoinduced charge transfer

I Kim, S Park, S Hong - Organic Letters, 2020 - ACS Publications
By exploiting electron donor–acceptor (EDA) complexes between 1, 4-dihydropyridines and
N-amidopyridinium salts under visible light irradiation, we discovered that photoinduced …

Visible-light-induced novel cyclization of 2-(2-(arylethynyl) benzylidene)-malononitrile derivatives with 2, 6-di (tert-butyl)-4-methylphenol to bridged spirocyclic …

X Xie, L Wang, Q Zhou, Y Ma, ZM Wang, P Li - Chinese Chemical Letters, 2022 - Elsevier
A green and highly efficient strategy for the preparation of bridged spirocyclic compounds
via visible-light-induced cyclization of 2-(2-(arylethynyl) benzylidene) malononitrile …