Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …

The activation and utilization of substrates mediated by Frustrated Lewis Pairs (FLPs) was
initially believed to occur solely via a two-electron, cooperative mechanism. More recently …

While conventional approaches to stabilizing main group radicals have involved the use of
Lewis acids or bases, this tutorial review focuses on new avenues to main group radicals …

Dielectric barrier discharge plasma (DBDP) is a promising advanced oxidation process for
water contaminants degradation relying on the coexistence of multiple reactive species …

An efficient B (C6F5) 3-catalyzed aerobic oxidative C–S cross-coupling reaction of
thiophenol with indoles was developed, affording a wide range of diaryl sulfides in good …

A stable cross-conjugated diradical was prepared by the reaction of a donor–acceptor–
donor (D–A–D) molecule with B (C6F5) 3. Its geometry and electronic structure were …

π‐Conjugated chiral nanorings with intriguing electronic structures and chiroptical
properties have attracted considerable interests in synthetic chemistry and materials …

This study, which aims to identify atypical platforms for the reduction of dioxygen, describes
the reaction of O2 with two distibines, namely, 4, 5-bis (diphenylstibino)-2, 7-di-tert-butyl-9, 9 …

Frustrated radical pairs (FRP) are expected to effectively combine radical chemistry and the
synergistic effects of a Lewis acid (LA) and Lewis base (LB), but this area is still in its primary …

Six directed hydrogen bonding (H-bonding) interactions allow for the reversible capture and
reduction of dioxygen to a trans-1, 2-peroxo within a tripodal zinc (II) framework …