Synthesis and Isomeric Analysis of RuII Complexes Bearing Pentadentate Scaffolds

M Gil-Sepulcre, JC Axelson, J Aguiló… - Inorganic …, 2016 - ACS Publications
A RuII-pentadentate polypyridyl complex [RuII (κ-N5-bpy2PYMe) Cl]+(1+, bpy2PYMe= 1-(2-
pyridyl)-1, 1-bis (6–2, 2′-bipyridyl) ethane) and its aqua derivative [RuII (κ-N5 …

Versatile Coordination of Azocarboxamides: Redox‐Triggered Change of the Chelating Binding Pocket in Ruthenium Complexes

J Klein, J Beerhues, D Schweinfurth… - … A European Journal, 2018 - Wiley Online Library
Azocarboxamides occupy a special place among azo ligands owing to their versatility for
metal coordination. Herein ruthenium complexes with two different azocarboxamide ligands …

Synthesis, structural characterization, antibacterial activity and computational studies of new cobalt (II) complexes with 1, 1, 3, 3-tetrakis (3, 5-dimethyl-1-pyrazolyl) …

A Beheshti, F Safaeiyan, F Hashemi… - Journal of Molecular …, 2016 - Elsevier
Two new mono-and dinuclear Co (II) complexes namely [Co (tdmpp) Cl 2] 2· H 2 O (1) and
[Co 2 (tdmpp) Cl 4](2)(where tdmpp= 1, 1, 3, 3-tetrakis (3, 5-dimethyl-1-pyrazolyl) propane) …

Formation of Iridium (III) Complexes via Selective Activation of the C–H and N–H Bonds of a Dipyridylpyrrole Ligand

M Xue, DL Zhuang, H Li, P He, C Liu, J Zhu… - Inorganic …, 2020 - ACS Publications
Treatment of [Ir (PPh3) 3Cl] with 2-[5-(pyridin-2-yl)-1 H-pyrrol-2-yl] pyridine (Hdpp) in
refluxing toluene affords an unexpected pyrrole-metalated iridium (III) hydride complex,[Ir …

Dinuclear Ruthenium Complexes Containing the Hpbl Ligand: Synthesis, Characterization, Linkage Isomerism, and Epoxidation Catalysis

L Francàs, RM González-Gil, D Moyano… - Inorganic …, 2014 - ACS Publications
Three dinucleating Ru–Cl complexes containing the hexadentate dinucleating ligand [1, 1′-
(4-methyl-1 H-pyrazole-3, 5-diyl) bis (1-(pyridin-2-yl) ethanol)](Hpbl) and the meridional 2 …

Electrochemical properties and C–H bond oxidation activity of [Ru (tpy)(pyalk) Cl]+ and [Ru (tpy)(pyalk)(OH)]+

CK Nilles, HNK Herath, H Fanous, A Ugrinov… - Dalton …, 2018 - pubs.rsc.org
[Ru (tpy)(pyalk) Cl] Cl (pyalk= 2-(2′-pyridyl)-2-propanol) was synthesized and
characterized crystallographically and electrochemically. Upon dissolution in water and …

Borate-based ligands with soft heterocycles and their ruthenium complexes

DK Roy, R Borthakur, S Bhattacharyya… - Journal of …, 2015 - Elsevier
In a quest for effective synthetic precursors for the preparation of B-agostic complexes of
ruthenium, we have shown that the reaction of [Cp* RuCl 2] 2 (Cp*= η5-C 5 Me 5) with [NaBt] …

DFT analysis of the linkage isomerism in penta (ammine) ruthenium (II/III) complexes of benzotriazole: Natural bond orbital method approach and a comprehensive …

TL da Costa Gouveia, RB Campos… - Journal of …, 2019 - Wiley Online Library
Penta (ammine) ruthenium benzotriazole complexes [RuII/III (NH3) 5bta]+/2+ and [RuII/III
(NH3) 5btaH] 2+/3+(bta and btaH are the deprotonated and neutral form of the triazole …