Metal-catalysed C–H bond activation and borylation

R Bisht, C Haldar, MMM Hassan, ME Hoque… - Chemical Society …, 2022 - pubs.rsc.org
Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …

N-Heterocyclic carbene complexes in C–H activation reactions

Q Zhao, G Meng, SP Nolan, M Szostak - Chemical reviews, 2020 - ACS Publications
In this contribution, we provide a comprehensive overview of C–H activation methods
promoted by NHC–transition metal complexes, covering the literature since 2002 (the year …

Mild metal-catalyzed C–H activation: examples and concepts

T Gensch, MN Hopkinson, F Glorius… - Chemical Society …, 2016 - pubs.rsc.org
Organic reactions that involve the direct functionalization of non-activated C–H bonds
represent an attractive class of transformations which maximize atom-and step-economy …

Recent advances in catalytic C− H borylation reactions

L Xu, G Wang, S Zhang, H Wang, L Wang, L Liu, J Jiao… - Tetrahedron, 2017 - Elsevier
In the past decades, the iridium-catalyzed C–H bond borylation and other newly discovered
catalytic borylation reactions have received extensive research interests and developed into …

Electrospun flexible nanofibres for batteries: design and application

PR Ilango, AD Savariraj, H Huang, L Li, G Hu… - Electrochemical Energy …, 2023 - Springer
Flexible and free-standing electrospun nanofibres have been used as electrode materials in
electrochemical energy storage systems due to their versatile properties, such as …

Metal-free regio-and chemoselective hydroboration of pyridines catalyzed by 1, 3, 2-diazaphosphenium triflate

B Rao, CC Chong, R Kinjo - Journal of the American Chemical …, 2018 - ACS Publications
N-Heterocyclic phosphenium triflates (NHP-OTf) 1 serve as efficient catalysts for the regio-
and chemoselective hydroboration of pyridines under ambient condition with good …

N, B-bidentate boryl ligand-supported iridium catalyst for efficient functional-group-directed C–H borylation

G Wang, L Liu, H Wang, YS Ding, J Zhou… - Journal of the …, 2017 - ACS Publications
Convenient silylborane precursors for introducing N, B-bidentate boryl ligands onto
transition metals were designed, prepared, and employed in ready formation of irdium (III) …

Tuning the structure and electronic properties of B–N fused dipyridylanthracene and implications on the self-sensitized reactivity with singlet oxygen

K Liu, RA Lalancette, F Jäkle - Journal of the American Chemical …, 2019 - ACS Publications
We demonstrate that the modification of anthracene with B← N Lewis pairs at their periphery
serves as a highly effective tool to modify the electronic structure with important ramifications …

Visible Light Induced Rhodium (I)‐Catalyzed C− H Borylation

J Thongpaen, R Manguin, V Dorcet, T Vives… - Angewandte …, 2019 - Wiley Online Library
An efficient visible light induced rhodium (I)‐catalyzed regioselective borylation of aromatic
C− H bonds is reported. The photocatalytic system is based on a single NHC− RhI complex …

Rhodium(I)-Catalyzed Aryl C–H Carboxylation of 2-Arylanilines with CO2

Y Gao, Z Cai, S Li, G Li - Organic letters, 2019 - ACS Publications
An unprecedented Rh (I)-catalyzed, amino-group-assisted C–H carboxylation of 2-
arylanilines with CO2 under redox-neutral conditions has been developed. This reaction …