From stable radicals to thermally robust high-spin diradicals and triradicals

C Shu, Z Yang, A Rajca - Chemical Reviews, 2023 - ACS Publications
Stable radicals and thermally robust high-spin di-and triradicals have emerged as important
organic materials due to their promising applications in diverse fields. New fundamental …

Electronic and Spintronic Open-Shell Macromolecules, Quo Vadis?

Y Tan, SN Hsu, H Tahir, L Dou, BM Savoie… - Journal of the …, 2022 - ACS Publications
Open-shell macromolecules (ie, polymers containing radical sites either along their
backbones or at the pendant sites of repeat units) have attracted significant attention owing …

Interface-engineered templates for molecular spin memory devices

KV Raman, AM Kamerbeek, A Mukherjee, N Atodiresei… - Nature, 2013 - nature.com
The use of molecular spin state as a quantum of information for storage, sensing and
computing has generated considerable interest in the context of next-generation data …

Perspective: Theory of quantum transport in molecular junctions

M Thoss, F Evers - The Journal of chemical physics, 2018 - pubs.aip.org
Molecular junctions, where single molecules are bound to metal or semiconductor
electrodes, represent a unique architecture to investigate molecules in a distinct …

Toward two‐dimensional π‐conjugated covalent organic radical frameworks

S Wu, M Li, H Phan, D Wang, TS Herng… - Angewandte Chemie …, 2018 - Wiley Online Library
Reported is the synthesis, characterization, and material properties of the first π‐conjugated
two‐dimensional covalent organic radical framework (CORF), PTM‐CORF, based on the …

Spin in density‐functional theory

CR Jacob, M Reiher - International Journal of Quantum …, 2012 - Wiley Online Library
The accurate description of open‐shell molecules, in particular of transition metal complexes
and clusters, is still an important challenge for quantum chemistry. Although density …

The first decade of organic spintronics research

D Sun, E Ehrenfreund, ZV Vardeny - Chemical communications, 2014 - pubs.rsc.org
The first decade of organic spintronics research has benefitted from the analogy and
previous experience of the inorganic spintronics field, coupled with the unlimited versatility …

Chiral-induced spin selectivity and non-equilibrium spin accumulation in molecules and interfaces: A first-principles study

S Naskar, V Mujica, C Herrmann - The Journal of Physical …, 2023 - ACS Publications
Electrons moving through chiral molecules are selected according to their spin orientation
and the helicity of the molecule, an effect known as chiral-induced spin selectivity (CISS) …

Radical Single-Molecule Junctions

L Li, CR Prindle, W Shi, C Nuckolls… - Journal of the …, 2023 - ACS Publications
Radicals are unique molecular systems for applications in electronic devices due to their
open-shell electronic structures. Radicals can function as good electrical conductors and …

Redox‐Addressable Single‐Molecule Junctions Incorporating a Persistent Organic Radical

S Naghibi, S Sangtarash, VJ Kumar… - Angewandte Chemie …, 2022 - Wiley Online Library
Integrating radical (open‐shell) species into non‐cryogenic nanodevices is key to unlocking
the potential of molecular electronics. While many efforts have been devoted to this issue, in …