Multimetallic catalysis based on heterometallic complexes and clusters

P Buchwalter, J Rosé, P Braunstein - Chemical reviews, 2015 - ACS Publications
Multimetallic catalysis is based on the combined action of different metals in a chemical
transformation. It has witnessed rapidly increasing developments during the past decades in …

Recent developments in asymmetric cyclopropanation

H Pellissier - Tetrahedron, 2008 - Elsevier
The importance of chirality is well recognised, mainly in connection with the fact that nearly
all natural products are chiral and their physiological or pharmacological properties depend …

Chiral gold nanoparticles

C Gautier, T Bürgi - ChemPhysChem, 2009 - Wiley Online Library
Nanoparticle chirality has attracted much attention recently, and the application of chiral
nanoparticles to chiral technologies (see figure) is also of interest. This Minireview deals …

Activation of unsaturated small molecules by bio-relevant multinuclear metal-sulfur clusters

K Tanifuji, S Ohta, Y Ohki, H Seino - Coordination Chemistry Reviews, 2023 - Elsevier
The high affinity of sulfur (S) for transition metal ions (M), as well as the flexible M− S
bonding and bridging modes, enable the formation of a wide range of multi-metallic …

Catalytic functions of cubane-type M 4 S 4 clusters

H Seino, M Hidai - Chemical Science, 2011 - pubs.rsc.org
Catalysis by the cubane-type Fe4S4 cluster has been found in metalloproteins such as
biotin synthase, aconitase, and IspH, whereas some synthetic M4S4 clusters show catalytic …

Tri-and tetranuclear molybdenum and tungsten chalcogenide clusters: On the way to new materials and catalysts

AL Gushchin, YA Laricheva… - Russian Chemical …, 2018 - iopscience.iop.org
Data on the electronic structure and redox, magnetic, luminescent, nonlinear optical and
catalytic properties of tri-and tetranuclear molybdenum and tungsten chalcogenide clusters …

Chalcogenide clusters of Group 5–7 metals

VE Fedorov, YV Mironov, NG Naumov… - Russian Chemical …, 2007 - iopscience.iop.org
The state-of-the-art and prospects of the development of chemistry of chalcogenide clusters
of Group 5–7 metals of the Periodic Table are discussed. The main structural types, methods …

Chiral metal cluster and nanocluster complexes and their application in asymmetric catalysis

QY Zhang, L Zhao - Tetrahedron Letters, 2018 - Elsevier
Chiral metal cluster and nanocluster complexes and their application in asymmetric catalysis -
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Efficient and Selective N‐Methylation of Nitroarenes under Mild Reaction Conditions

E Pedrajas, I Sorribes, E Guillamón… - … A European Journal, 2017 - Wiley Online Library
Herein, we report a straightforward protocol for the preparation of N, N‐dimethylated amines
from readily available nitro starting materials using formic acid as a renewable C1 source …

Highly Efficient and Regioselective Allylation with Allylic Alcohols Catalyzed by [Mo3S4Pd(η3-allyl)] Clusters

Y Tao, B Wang, B Wang, L Qu, J Qu - Organic Letters, 2010 - ACS Publications
A highly efficient and regioselective allylation reaction of amines and active methylene
compounds directly using allylic alcohols under mild conditions catalyzed by the novel …