Metal–organic framework glass composites

R Lin, M Chai, Y Zhou, V Chen, TD Bennett… - Chemical Society …, 2023 - pubs.rsc.org
The melting phenomenon in metal–organic frameworks (MOFs) has been recognised as
one of the fourth generation MOF paradigm behaviours. Molten MOFs have high …

Defect-enabling zirconium-based metal–organic frameworks for energy and environmental remediation applications

S Daliran, AR Oveisi, CW Kung, U Sen… - Chemical Society …, 2024 - pubs.rsc.org
This comprehensive review explores the diverse applications of defective zirconium-based
metal–organic frameworks (Zr-MOFs) in energy and environmental remediation. Zr-MOFs …

Interfacial Bonding between a Crystalline Metal–Organic Framework and an Inorganic Glass

C Castillo-Blas, AM Chester, RP Cosquer… - Journal of the …, 2023 - ACS Publications
The interface within a composite is critically important for the chemical and physical
properties of these materials. However, experimental structural studies of the interfacial …

Breaking the photoswitch speed limit

GC Thaggard, KC Park, J Lim… - Nature …, 2023 - nature.com
The forthcoming generation of materials, including artificial muscles, recyclable and
healable systems, photochromic heterogeneous catalysts, or tailorable supercapacitors …

Modeling the Effect of Defects and Disorder in Amorphous Metal–Organic Frameworks

I Bechis, AF Sapnik, A Tarzia, EH Wolpert… - Chemistry of …, 2022 - ACS Publications
Amorphous metal–organic frameworks (a MOFs) are a class of disordered framework
materials with a defined local order given by the connectivity between inorganic nodes and …

Mapping nanocrystalline disorder within an amorphous metal–organic framework

AF Sapnik, C Sun, JEM Laulainen… - Communications …, 2023 - nature.com
Intentionally disordered metal–organic frameworks (MOFs) display rich functional behaviour.
However, the characterisation of their atomic structures remains incredibly challenging. X …

Structural insights into hybrid immiscible blends of metal–organic framework and sodium ultraphosphate glasses

AM Chester, C Castillo-Blas, R Sajzew… - Chemical …, 2023 - pubs.rsc.org
Recently, increased attention has been focused on amorphous metal–organic frameworks
(MOFs) and, more specifically, MOF glasses, the first new glass category discovered since …

In situ studies of the formation of tungsten and niobium oxide nanoparticles: towards automated analysis of reaction pathways from PDF analysis using the Pearson …

ETS Kjær, O Aalling‐Frederiksen, L Yang… - Chemistry …, 2022 - Wiley Online Library
Abstract Using Pair Distribution Function (PDF) analysis of in situ total scattering data, we
investigate the formation of tungsten and niobium oxides in a simple solvothermal synthesis …

Computational modeling to assist in the discovery of supramolecular materials

KE Jelfs - Annals of the New York Academy of Sciences, 2022 - Wiley Online Library
Computational modeling is increasingly used to assist in the discovery of supramolecular
materials. Supramolecular materials are typically primarily built from organic components …

Synthetic and analytical considerations for the preparation of amorphous metal–organic frameworks

EV Shaw, AM Chester, GP Robertson… - Chemical …, 2024 - pubs.rsc.org
Metal–organic frameworks (MOFs) are hybrid porous materials presenting several tuneable
properties, allowing them to be utilised for a wide range of applications. To date, focus has …