Overcoming the “Oxidant Problem”: Strategies to Use O2 as the Oxidant in Organometallic C–H Oxidation Reactions Catalyzed by Pd (and Cu)

AN Campbell, SS Stahl - Accounts of Chemical Research, 2012 - ACS Publications
Oxidation reactions are key transformations in organic chemistry because they can increase
chemical complexity and incorporate heteroatom substituents into carbon-based molecules …

Synthesis and functionalization of indoles through palladium-catalyzed reactions

S Cacchi, G Fabrizi - Chemical reviews, 2005 - ACS Publications
The substituted indole nucleus [indole is the acronym from indigo (the natural dye) and
oleum (used for the isolation)] is a structural component of a vast number of biologically …

Carboxylic acids as substrates in homogeneous catalysis

LJ Gooßen, N Rodríguez… - Angewandte Chemie …, 2008 - Wiley Online Library
In organic molecules carboxylic acid groups are among the most common functionalities.
Activated derivatives of carboxylic acids have long served as versatile connection points in …

C−C, C−O, C−N Bond Formation on sp2 Carbon by Pd(II)-Catalyzed Reactions Involving Oxidant Agents

EM Beccalli, G Broggini, M Martinelli… - Chemical …, 2007 - ACS Publications
The transformation of unsaturated hydrocarbons through the action of metal complexes
continues to constitute a very important field of organometallic chemistry, particularly when …

Intermolecular dehydrogenative Heck reactions

J Le Bras, J Muzart - Chemical Reviews, 2011 - ACS Publications
The Pd-catalyzed reaction of an aryl halide with an alkene affords, in most cases, the
corresponding arylalkene. It is usually considered that this reaction, which is called the Heck …

Catalytic oxidation of organic substrates by molecular oxygen and hydrogen peroxide by multistep electron transfer—a biomimetic approach

J Piera, JE Bäckvall - Angewandte Chemie International …, 2008 - Wiley Online Library
Oxidation reactions are of fundamental importance in nature, and are key transformations in
organic synthesis. The development of new processes that employ transition metals as …

<? ACS-CT-START-Insert?> Update 1 of:<? ACS-CT-END-Insert?> Synthesis and Functionalization of Indoles Through Palladium-Catalyzed Reactions

S Cacchi, G Fabrizi - Chemical Reviews, 2011 - ACS Publications
The substituted indole nucleus [indole is the acronym fromindigo (the natural dye) and
oleum (used for the isolation)] is a structural component of a vast number of biologically …

A rule to predict which enantiomer of a secondary alcohol reacts faster in reactions catalyzed by cholesterol esterase, lipase from Pseudomonas cepacia, and lipase …

RJ Kazlauskas, ANE Weissfloch… - The Journal of …, 1991 - ACS Publications
The enantioselectivity of the title enzymes for more than 130 esters of secondary alcohols is
correlated by a rule based on the sizes of the substituents at the stereocenter. This rule …

Fine feathers make fine birds: The Heck reaction in modern garb

A De Meijere, FE Meyer - Angewandte Chemie International …, 1995 - Wiley Online Library
The palladium‐catalyzed coupling of haloarenes and haloalkenes with alkenes, which was
discovered by Richard F. Heck in the late sixties, has been a topic of fluctuating interest; …

[图书][B] Dictionary of natural products, Supplement 2

J Buckingham - 2023 - taylorfrancis.com
Containing fully authenticated data on virtually all known natural products, the" Dictionary of
Natural Products", main work, published in 1993 was the end result of over 12 years …