Quantum control of molecular rotation

CP Koch, M Lemeshko, D Sugny - Reviews of Modern Physics, 2019 - APS
The angular momentum of molecules, or, equivalently, their rotation in three-dimensional
space, is ideally suited for quantum control. Molecular angular momentum is naturally …

Ultrafast chirality: the road to efficient chiral measurements

D Ayuso, AF Ordonez, O Smirnova - Physical Chemistry Chemical …, 2022 - pubs.rsc.org
Today we are witnessing the electric–dipole revolution in chiral measurements. Here we
reflect on its lessons and outcomes, such as the perspective on chiral measurements using …

Single-shot nondestructive quantum sensing for gaseous samples with hundreds of chiral molecules

C Ye, Y Sun, Y Li, X Zhang - The Journal of Physical Chemistry …, 2023 - ACS Publications
Chiral discrimination that is efficient at detecting tiny amounts of chiral substances,
especially at the single-molecule level, is in great demand. Here, we propose a single-shot …

Coherent Enantiomer‐Selective Population Enrichment Using Tailored Microwave Fields

C Pérez, AL Steber, SR Domingos… - Angewandte Chemie …, 2017 - Wiley Online Library
We report the experimental demonstration of coherent enantiomer‐selective enrichment of
chiral molecules by employing a novel microwave five‐pulse scheme. Our results show that …

Highly efficient detection and separation of chiral molecules through shortcuts to adiabaticity

NV Vitanov, M Drewsen - Physical Review Letters, 2019 - APS
A highly efficient method for optical or microwave detection and separation of left-and right-
handed chiral molecules is proposed. The method utilizes a closed-loop three-state system …

Accuracy of quantum chemistry structures of chiral tag complexes and the assignment of absolute configuration

K Mayer, C West, FE Marshall, G Sedo… - Physical Chemistry …, 2022 - pubs.rsc.org
The absolute configuration of a molecule can be established by analysis of molecular
rotational spectra of the analyte complexed with a small chiral molecule of known …

Advances and unresolved challenges in the structural characterization of isomeric lipids

SE Hancock, BLJ Poad, A Batarseh, SK Abbott… - Analytical …, 2017 - Elsevier
As the field of lipidomics grows and its application becomes wide and varied it is important
that we don't forget its foundation, ie the identification and measurement of molecular lipids …

Machine-Learning Enhanced Enantioselective Single-Shot-Single-Molecule ac Stark Spectroscopy

X Mu, C Ye, X Zhang - The Journal of Physical Chemistry Letters, 2023 - ACS Publications
Enantiodiscrimination with single-molecule and single-shot resolution is fundamental for the
understanding of the fate and behavior of two enantiomers in chemical reactions, biological …

Assessing the performance of rotational spectroscopy in chiral analysis

SR Domingos, C Pérez, MD Marshall, HO Leung… - Chemical …, 2020 - pubs.rsc.org
The capabilities of rotational spectroscopy-based methods as tools to deliver accurate and
precise chirality-sensitive information are still breaking ground, but their applicability in the …

Chiral analysis of pantolactone with molecular rotational resonance spectroscopy

RE Sonstrom, JL Neill, AV Mikhonin, R Doetzer… - Chirality, 2022 - Wiley Online Library
A molecular rotational resonance spectroscopy method for measuring the enantiomeric
excess of pantolactone, an intermediate in the synthesis of panthenol and pantothenic acid …