Open-shell molecules such as radicals, carbenes, and electronically excited-state molecules
exhibit high energies, and thus, in general, they are quite reactive. 1 The short-lived species …

This review article provides a survey of contemporary investigations on main group metal
cluster formation, addressing homo‐and heterometallic clusters (including small numbers of …

Main‐group singlet biradicaloids have been thoroughly investigated in the past two
decades, especially derivatives of cyclobutane‐1, 3‐diyl. However, in each of the known …

Abstract Alkyltin trihydride [(Me3Si) 2CHSnH3] was synthesized and the reductive
elimination of hydrogen from this species was investigated. A methyl‐substituted N …

Pyramidane is an elusive but highly desirable target for synthetic chemists that has attracted
a great deal of attention because of its nonclassical structure and unusual bonding features …

The mixed heteroadamantanes Si6Ge4 and Si6Sn4 are readily accessible from
Me2ECl2/Si2Cl6/cat. Cl−(4× EMe2, 2× SiCl2, 4× Si–SiCl3 vertices; E= Ge, Sn). Different …

The oxidation of K [Ge9 (Hyp) 3](Hyp= Si (SiMe3) 3) with lanthanide triiodides LnI3 (Ln= Eu,
Sm, Yb) leads to the formation of novel clusters with a Ge18-core isolated as a co …

A reaction of antimonytrichloride SbCl3 with potassium bis (terphenylimino) phosphide K
[(TerN) 2P] smoothly afforded a novel class of mixed diazadipnictanes, namely dichloro …

Abstract Singulett‐Biradikaloide der Hauptgruppenelemente wurden in den letzten 20
Jahren gründlich untersucht, insbesondere Derivate des Cyclobutan‐1, 3‐diyls. Jedoch sind …

(trip2Sn) 2 (trip= 2, 4, 6-i-Pr3C6H2) reacts with Mg (I) reductants (LMg) 2 (L= HC [C (Me) N
(dipp)] 2) and (L′ Mg) 2 (L′= HC [C (Me) N (mes)] 2) with Sn–C bond cleavage and …