[HTML][HTML] Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time

A Zabala-Lekuona, JM Seco, E Colacio - Coordination Chemistry Reviews, 2021 - Elsevier
The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …

Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Lanthanide single-molecule magnets

DN Woodruff, REP Winpenny, RA Layfield - Chemical reviews, 2013 - ACS Publications
In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …

An air-stable Dy (III) single-ion magnet with high anisotropy barrier and blocking temperature

SK Gupta, T Rajeshkumar, G Rajaraman… - Chemical …, 2016 - pubs.rsc.org
Herein we report air-stable Dy (III) and Er (III) single-ion magnets (SIMs) with pseudo-D5h
symmetry, synthesized from a sterically encumbered phosphonamide, tBuPO (NHiPr) 2 …

Record quantum tunneling time in an air-stable exchange-bias dysprosium macrocycle

Z Zhu, S Paul, C Zhao, J Wu, X Ying… - Journal of the …, 2024 - ACS Publications
In recent years, dysprosium macrocycle single-molecule magnets (SMMs) have received
increasing attention due to their excellent air/thermal stability, strong magnetic anisotropy …

Multifunctional Helicene‐Based Ytterbium Coordination Polymer Displaying Circularly Polarized Luminescence, Slow Magnetic Relaxation and Room Temperature …

K Dhbaibi, M Grasser, H Douib, V Dorcet… - Angewandte …, 2023 - Wiley Online Library
The combination of physical properties sensitive to molecular chirality in a single system
allows the observation of fascinating phenomena such as magneto‐chiral dichroism (MChD) …

Giant coercivity and high magnetic blocking temperatures for N23− radical-bridged dilanthanide complexes upon ligand dissociation

S Demir, MI Gonzalez, LE Darago, WJ Evans… - Nature …, 2017 - nature.com
Increasing the operating temperatures of single-molecule magnets—molecules that can
retain magnetic polarization in the absence of an applied field—has potential implications …

Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies

P Zhang, YN Guo, J Tang - Coordination Chemistry Reviews, 2013 - Elsevier
The last few years have seen a huge renaissance in the study of the magnetism of
lanthanide coordination complexes, especially in the field of single molecule magnets …

An electrostatic model for the determination of magnetic anisotropy in dysprosium complexes

NF Chilton, D Collison, EJL McInnes… - Nature …, 2013 - nature.com
Understanding the anisotropic electronic structure of lanthanide complexes is important in
areas as diverse as magnetic resonance imaging, luminescent cell labelling and quantum …

Strong Axiality and Ising Exchange Interaction Suppress Zero-Field Tunneling of Magnetization of an Asymmetric Dy2 Single-Molecule Magnet

YN Guo, GF Xu, W Wernsdorfer, L Ungur… - Journal of the …, 2011 - ACS Publications
The high axiality and Ising exchange interaction efficiently suppress quantum tunneling of
magnetization of an asymmetric dinuclear DyIII complex, as revealed by combined …