Emerging Trends in Cross-Coupling: Twelve-Electron-Based L1Pd(0) Catalysts, Their Mechanism of Action, and Selected Applications

SJ Firsan, V Sivakumar, TJ Colacot - Chemical Reviews, 2022 - ACS Publications
Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

Conducting polymers for optoelectronic devices and organic solar cells: A review

A R. Murad, A Iraqi, SB Aziz, S N. Abdullah, MA Brza - Polymers, 2020 - mdpi.com
In this review paper, we present a comprehensive summary of the different organic solar cell
(OSC) families. Pure and doped conjugated polymers are described. The band structure …

Solvent effects in palladium catalysed cross-coupling reactions

J Sherwood, JH Clark, IJS Fairlamb, JM Slattery - Green Chemistry, 2019 - pubs.rsc.org
Palladium catalysed cross-couplings reactions have been a dominant method in synthetic
chemistry for decades. Despite this, the role of the solvent is often taken for granted and …

Computational studies of synthetically relevant homogeneous organometallic catalysis involving Ni, Pd, Ir, and Rh: an overview of commonly employed DFT methods …

T Sperger, IA Sanhueza, I Kalvet… - Chemical …, 2015 - ACS Publications
The field of organometallic catalysis has attracted considerable interest from both academia
and industry due to its broad applications in synthetic transformations. Pd, Ni, Rh, and Ir …

The Stille reaction, 38 years later

C Cordovilla, C Bartolomé, JM Martinez-Ilarduya… - Acs …, 2015 - ACS Publications
The first now-named Stille reaction was published 38 years ago, and the last comprehensive
revision of this catalysis was in 2004. Since then, the knowledge of the different steps of the …

Recent developments in Negishi cross-coupling reactions

D Haas, JM Hammann, R Greiner, P Knochel - ACS Catalysis, 2016 - ACS Publications
This Perspective describes general methods for the preparation of polyfunctional zinc
organometallics and their use in Negishi cross-coupling reactions. Recent advances …

Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link

AA Thomas, SE Denmark - Science, 2016 - science.org
Despite the widespread application of Suzuki-Miyaura cross-coupling to forge carbon-
carbon bonds, the structure of the reactive intermediates underlying the key transmetalation …

Nano-palladium is a cellular catalyst for in vivo chemistry

MA Miller, B Askevold, H Mikula, RH Kohler… - Nature …, 2017 - nature.com
Palladium catalysts have been widely adopted for organic synthesis and diverse industrial
applications given their efficacy and safety, yet their biological in vivo use has been limited …

Palladium-catalyzed cross-coupling reactions of organoboron compounds

N Miyaura, A Suzuki - Chemical reviews, 1995 - ACS Publications
Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds Page 1 Chem.
Rev. 1995, 95, 2457-2483 2457 Palladium-Catalyzed Cross-Coupling Reactions of …

Aryl− aryl bond formation one century after the discovery of the Ullmann reaction

J Hassan, M Sévignon, C Gozzi, E Schulz… - Chemical …, 2002 - ACS Publications
Arylraryl bond formation is one of the most important tools of modern organic synthesis.
These bonds are very often found in natural products such as alkaloids as well as in …