Comprehensive overview of polyoxometalates for electrocatalytic hydrogen evolution reaction

Z Zeb, Y Huang, L Chen, W Zhou, M Liao… - Coordination Chemistry …, 2023 - Elsevier
Electrocatalytic water splitting via hydrogen evolution reaction (HER) from renewable energy
sources is an attractive alternative to produce hydrogen, but it still encounters the limitations …

Polyoxometalates (POMs): from electroactive clusters to energy materials

MR Horn, A Singh, S Alomari… - Energy & …, 2021 - pubs.rsc.org
Polyoxometalates (POMs) represent a class of nanomaterials, which hold enormous
promise for a range of energy-related applications. Their promise is owing to their “special” …

Heteropoly acid negolytes for high-power-density aqueous redox flow batteries at low temperatures

F Ai, Z Wang, NC Lai, Q Zou, Z Liang, YC Lu - Nature Energy, 2022 - nature.com
Operating aqueous redox flow batteries (ARFBs) at low temperatures is prohibited by limited
solubility of redox-active materials, freezing electrolytes and sluggish reaction kinetics. Here …

Recent progress in metal-organic frameworks as active materials for supercapacitors

KB Wang, Q Xun, Q Zhang - EnergyChem, 2020 - Elsevier
Abstract Metal-organic frameworks (MOFs), also quoted as porous coordination polymers
(PCPs), are causing great concern in supercapacitors (SCs) field owing to their ultra-high …

POM-incorporated ZnIn2S4 Z-scheme dual-functional photocatalysts for cooperative benzyl alcohol oxidation and H2 evolution in aqueous solution

F Xing, R Zeng, C Cheng, Q Liu, C Huang - Applied Catalysis B …, 2022 - Elsevier
Efficient aromatic alcohol oxidation with simultaneous H 2 evolution under aqueous
conditions is achieved in a polyoxometalate (POM)-incorporated ZnIn 2 S 4 dual-functional …

Demystifying the roles of single metal site and cluster in CO2 reduction via light and electric dual-responsive polyoxometalate-based metal-organic frameworks

Q Huang, Q Niu, XF Li, J Liu, SN Sun, LZ Dong… - Science …, 2022 - science.org
Photo-or electroreduction of carbon dioxide into highly valued products offers a promising
strategy to achieve carbon neutrality. Here, a series of polyoxometalate-based metal-organic …

O-coordinated W-Mo dual-atom catalyst for pH-universal electrocatalytic hydrogen evolution

Y Yang, Y Qian, H Li, Z Zhang, Y Mu, D Do, B Zhou… - Science …, 2020 - science.org
Single-atom catalysts (SACs) maximize the utility efficiency of metal atoms and offer great
potential for hydrogen evolution reaction (HER). Bimetal atom catalysts are an appealing …

Three mechanisms in one material: uranium capture by a polyoxometalate–organic framework through combined complexation, chemical reduction, and …

H Zhang, W Liu, A Li, D Zhang, X Li… - Angewandte Chemie …, 2019 - Wiley Online Library
The design and synthesis of uranium sorbent materials with high uptake efficiency, capacity
and selectivity, as well as excellent hydrolytic stability and radiation resistance remains a …

Synthesis, structures and applications of electron-rich polyoxometalates

NI Gumerova, A Rompel - Nature Reviews Chemistry, 2018 - nature.com
Ever since the discovery and development of polyoxometalates (POMs), it has been known
that they can exist in electron-rich reduced forms of different archetypes, structural …

Recent advances in confining polyoxometalates and the applications

L Guo, L He, Q Zhuang, B Li, C Wang, Y Lv, J Chu… - Small, 2023 - Wiley Online Library
Polyoxometalates (POMs) are widely used in catalysis, energy storage, biomedicine, and
other research fields due to their unique acidity, photothermal, and redox features. However …