Methane oxidation to methanol

NF Dummer, DJ Willock, Q He, MJ Howard… - Chemical …, 2022 - ACS Publications
The direct transformation of methane to methanol remains a significant challenge for
operation at a larger scale. Central to this challenge is the low reactivity of methane at …

[HTML][HTML] Strategies toward the sustainable electrochemical oxidation of methane to methanol

JA Arminio-Ravelo, M Escudero-Escribano - Current Opinion in Green and …, 2021 - Elsevier
The direct conversion of methane to methanol is very promising to achieve a decarbonized
future, but remains a great challenge. The electrochemical activation and partial oxidation of …

Electrochemical conversion of methane to bridge the gap in the artificial carbon cycle

Y Peng, Y Song, I Razanau, J Xiao, W Xiao… - Journal of Energy …, 2024 - Elsevier
Methane, an abundant one-carbon (C 1) resource, is extensively used in the industrial
production of vital fuels and value-added chemicals. However, current industrial methane …

Isolated metal atoms and clusters for alkane activation: Translating knowledge from enzymatic and homogeneous to heterogeneous systems

L Liu, A Corma - Chem, 2021 - cell.com
Activation of alkanes can be achieved with different types of catalysts, spanning over
enzymes, homogeneous and heterogeneous metal catalysts. Though a tremendous amount …

Electrochemical methane conversion

Q Wang, M Kan, Q Han, G Zheng - Small Structures, 2021 - Wiley Online Library
Methane, as an earth‐abundant C1 resource, is a greenhouse gas as well as a key building
block in the chemical industry. Electrochemical conversion of methane into fuels and …

Low-Temperature Electrochemical Oxidation of Methane into Alcohols

A Mehmood, SY Chae, ED Park - Catalysts, 2024 - mdpi.com
The direct oxidation of methane to methanol is considered challenging due to the
intrinsically low reactivity of the C–H bond of methane and the formation of a large number of …

Theory and experiment demonstrate that Sb (V)-Promoted methane C–H activation and functionalization outcompete superacid protonolysis in sulfuric acid

SS Chen, A Koppaka, RA Periana… - Journal of the American …, 2021 - ACS Publications
Sb (V) in strong Brønsted acid solvents is traditionally assumed to react with light alkanes
through superacid protonolysis, which results in carbocation intermediates, H2, and carbon …

Electrocatalytic Methane Functionalization with d0 Early Transition Metals Under Ambient Conditions

J Deng, SC Lin, JT Fuller III, B Zandkarimi… - Angewandte …, 2021 - Wiley Online Library
The undesirable loss of methane (CH4) at remote locations welcomes approaches that
ambiently functionalize CH4 on‐site without intense infrastructure investment. Recently, we …

AgII‐Mediated Electrocatalytic Ambient CH4 Functionalization Inspired by HSAB Theory

D Xiang, JA Iñiguez, J Deng, X Guan… - Angewandte Chemie …, 2021 - Wiley Online Library
Although most class (b) transition metals have been studied in regard to CH4 activation,
divalent silver (AgII), possibly owing to its reactive nature, is the only class (b) high‐valent …

Recent Progress in Electrochemical Conversion from Biomass Derivatives into High‐Value‐Added Chemicals

Y Sun, J Miao, X Fan, K Zhang, T Zhang - Small Structures, 2024 - Wiley Online Library
Selective and efficient electrochemical conversion of cheap and abundant biomass
derivatives into high‐value‐added products can provide a way to store large‐scale …