Recent advances in the theory and molecular simulation of biological electron transfer reactions

J Blumberger - Chemical reviews, 2015 - ACS Publications
1. INTRODUCTION AND OVERVIEW The transfer and transport of electrons through
biological matter is one of the key steps underlying cellular energy harvesting, storage, and …

Biochemistry and theory of proton-coupled electron transfer

A Migliore, NF Polizzi, MJ Therien… - Chemical reviews, 2014 - ACS Publications
Through incremental change, Nature reworks and repurposes its functional machinery. In
this way, proteins that photochemically repair DNA by moving protons and electrons have a …

Polariton-mediated electron transfer via cavity quantum electrodynamics

A Mandal, TD Krauss, P Huo - The Journal of Physical Chemistry …, 2020 - ACS Publications
We investigate the polariton-mediated electron transfer reaction in a model system with
analytic rate constant theory and direct quantum dynamical simulations. We demonstrate …

Free charge carriers in homo-sorted π-stacks of donor–acceptor conjugates

M Madhu, R Ramakrishnan, V Vijay… - Chemical …, 2021 - ACS Publications
Inspired by the high photoconversion efficiency observed in natural light-harvesting systems,
the hierarchical organization of molecular building blocks has gained impetus in the past …

[图书][B] Quantum effects in biology

M Mohseni, Y Omar, GS Engel, MB Plenio - 2014 - books.google.com
Quantum mechanics provides the most accurate microscopic description of the world around
us, yet the interface between quantum mechanics and biology is only now being explored …

Coherence in Chemistry: Foundations and Frontiers

JD Schultz, JL Yuly, EA Arsenault, K Parker… - Chemical …, 2024 - ACS Publications
Coherence refers to correlations in waves. Because matter has a wave-particle nature, it is
unsurprising that coherence has deep connections with the most contemporary issues in …

Interplay of vibrational wavepackets during an ultrafast electron transfer reaction

SR Rather, B Fu, B Kudisch, GD Scholes - Nature chemistry, 2021 - nature.com
Electron transfer reactions facilitate energy transduction and photoredox processes in
biology and chemistry. Recent findings show that molecular vibrations can enable the …

Bioinspired Catalyst Design Principles: Progress in Emulating Properties of Enzymes in Synthetic Catalysts

B Ginovska, OY Gutiérrez, A Karkamkar, MS Lee… - ACS …, 2023 - ACS Publications
Catalysis enables many aspects of modern life, including fuels, products, plastics, and
medicines. Recent advances in catalysis have enabled us to realize higher efficiencies and …

Toward control of electron transfer in donor-acceptor molecules by bond-specific infrared excitation

M Delor, PA Scattergood, IV Sazanovich, AW Parker… - Science, 2014 - science.org
Electron transfer (ET) from donor to acceptor is often mediated by nuclear-electronic
(vibronic) interactions in molecular bridges. Using an ultrafast electronic-vibrational …

Charge transfer in dynamical biosystems, or the treachery of (static) images

DN Beratan, C Liu, A Migliore, NF Polizzi… - Accounts of chemical …, 2015 - ACS Publications
Conspectus The image is not the thing. Just as a pipe rendered in an oil painting cannot be
smoked, quantum mechanical coupling pathways rendered on LCDs do not convey …