A Mechanistic Insight into the Oxygen Redox of Li‐Rich Layered Cathodes and their Related Electronic/Atomic Behaviors Upon Cycling

S Kang, D Choi, H Lee, B Choi, YM Kang - Advanced Materials, 2023 - Wiley Online Library
Li‐rich cathodes are extensively investigated as their energy density is superior to Li
stoichiometric cathode materials. In addition to the transition metal redox, this intriguing …

Review of the US Department of Energy's “deep dive” effort to understand voltage fade in Li-and Mn-rich cathodes

JR Croy, M Balasubramanian… - Accounts of chemical …, 2015 - ACS Publications
Conspectus The commercial introduction of the lithium-ion (Li-ion) battery nearly 25 years
ago marked a technological turning point. Portable electronics, dependent on energy …

Phosphate polyanion materials as high-voltage lithium-ion battery cathode: a review

JK Ling, C Karuppiah, SG Krishnan, MV Reddy… - Energy & …, 2021 - ACS Publications
Followed by decades of successful efforts in developing cathode materials for high specific
capacity lithium-ion batteries, currently the attention is on developing a high-voltage battery …

Recent achievements on inorganic electrode materials for lithium-ion batteries

L Croguennec, MR Palacin - Journal of the American Chemical …, 2015 - ACS Publications
The lithium-ion battery technology is rooted in the studies of intercalation of guest ions into
inorganic host materials developed ca. 40 years ago. It further turned into a commercial …

Lithium‐and manganese‐rich oxide cathode materials for high‐energy lithium ion batteries

J Wang, X He, E Paillard, N Laszczynski… - Advanced energy …, 2016 - Wiley Online Library
Layered lithium‐and manganese‐rich oxides (LMROs), described as xLi2MnO3·(1–x)
LiMO2 or Li1+ yM1–yO2 (M= Mn, Ni, Co, etc., 0< x< 1, 0< y≤ 0.33), have attracted much …

In situ probing and synthetic control of cationic ordering in Ni‐Rich layered oxide cathodes

J Zhao, W Zhang, A Huq, ST Misture… - Advanced Energy …, 2017 - Wiley Online Library
Ni‐rich layered oxides (LiNi1–xMxO2; M= Co, Mn,…) are appealing alternatives to
conventional LiCoO2 as cathodes in Li‐ion batteries for automobile and other large‐scale …

Nanocomposite Engineering of a High‐Capacity Partially Ordered Cathode for Li‐Ion Batteries

E Lee, TU Wi, J Park, SW Park, MH Kim… - Advanced …, 2023 - Wiley Online Library
Understanding the local cation order in the crystal structure and its correlation with
electrochemical performances has advanced the development of high‐energy Mn‐rich …

Effects of cation superstructure ordering on oxygen redox stability in O2-type lithium-rich layered oxides

D Eum, HY Jang, B Kim, J Chung, D Kim… - Energy & …, 2023 - pubs.rsc.org
Archetypical layered oxide with oxygen redox capability bears an additional lithium ion in a
transition metal layer, and its local coordination with oxygen is crucial in triggering the …

Recent advances and remaining challenges for lithium ion battery cathodes

EM Erickson, F Schipper, TR Penki… - Journal of The …, 2017 - iopscience.iop.org
Electrodes prepared from lithium-rich (Li-rich) xLi 2 MnO 3⋅(1-x) LiNi a Co b Mn c O 2
materials (a+ b+ c= 1) show extremely high discharge capacities, arising from excess Li+ …

Re-entrant lithium local environments and defect driven electrochemistry of Li-and Mn-rich Li-ion battery cathodes

F Dogan, BR Long, JR Croy, KG Gallagher… - Journal of the …, 2015 - ACS Publications
Direct observations of structure–electrochemical activity relationships continue to be a key
challenge in secondary battery research. 6Li magic angle spinning (MAS) nuclear magnetic …