Metal–organic frameworks (MOFs) represent a novel class of crystalline inorganic–organic
hybrid materials with tunable semiconducting behavior. MOFs have potential for application …

As one of the most fundamental substances in modern organic synthesis, ammonia is an
essential feedstock for the production of nitrogenous fertilizers and other chemicals …

The development of efficient photocatalysts for N2 fixation to produce NH3 under ambient
conditions remains a great challenge. Since covalent organic frameworks (COFs) possess …

Modulation of the local electronic structure and microenvironment of catalytic metal sites
plays a critical role in electrocatalysis, yet remains a grand challenge. Herein, PdCu …

Constructing MOF‐on‐MOF heterojunction with elaborate charge transfer mechanism and
interface is a promising strategy for improving the photocatalytic properties of MOFs. Herein …

This work reports that a low‐temperature thermal calcination strategy was adopted to
modulate the electronic structure and attain an abundance of surface‐active sites while …

Piezo‐photocatalysis is a frontier technology for converting mechanical and solar energies
into crucial chemical substances and has emerged as a promising and sustainable strategy …

Rapid recombination of interfacial charges is considered to be the main obstacle limiting N 2
photofixation. It is urgent but challenging to develop a precise and stable strategy to steer …

In nature, nitrogenase can achieve efficient environmental fixation of nitrogen (N2)
molecules through π-backbonding mechanism, which inspires us to simulate the N2 fixation …

Metal organic framework (MOF)-based photocatalysts for solar-driven fuel generation have
seen significant advancement owing to their structural and porous controllability, high …