The principle of vinylogy states that the electronic effects of a functional group in a molecule
are possibly transmitted to a distal position through interposed conjugated multiple bonds …

The catalytic asymmetric synthesis of 3, 3-disubstituted oxindoles, a big family of privileged
scaffolds in natural products and drugs, is of current interest. Recently, the catalytic …

Chiral hydrogen‐bonding (H‐bonding) catalytic asymmetric conjugate addition to activated
olefins has been widely used to access enantioenriched molecules containing stereocenters …

Compared to γ‐addition, the α‐addition of α‐branched β, γ‐unsaturated aldehydes faces
larger steric hindrance and disrupts the π–π conjugation, which might be why very few …

Catalytic asymmetric cycloadditions via transition-metal-containing dipolar intermediates are
a powerful tool for synthesizing chiral heterocycles. However, within the field of palladium …

Chiral (dihydro) furo‐fused heterocycles are significant structural motifs in numerous natural
products, functional materials and pharmaceuticals. Therefore, developing efficient methods …

Remote control of the axial chirality of N-(2-t-butylphenyl) succinimides was realized via the
vinylogous Michael addition of 3-substituted cyclohexenones to N-(2-t-butylphenyl) …

A highly efficient and practical one-pot sequential process, consisting of an organocatalytic
enantioselective Friedel–Crafts-type addition of 4-nonsubstituted pyrazolones to isatin …

Developing innovative dynamic kinetic resolution (DKR) modes and achieving the highly
regio-and enantioselective semihydrogenation of unsymmetrical α-diketones are two …

Abstract Synthetically versatile 3, 3‐disubstituted fluorooxindoles exhibiting vicinal chirality
centers were obtained in high yields and with excellent enantio‐, diastereo‐, and …