BACKGROUND Since the work of Sabatier 100 year ago, chemists have turned almost
exclusively to metals to activate H2 by weakening or cleaving its central bond. This …

A survey of protein databases indicates that the majority of enzymes exist in oligomeric
forms, with about half of those found in the UniProt database being homodimeric …

Supported nanoparticles containing more than one metal have a variety of applications in
sensing, catalysis, and biomedicine. Common synthesis techniques for this type of material …

Transition metals can assemble to form multinuclear complexes by engaging in direct metal-
to-metal interactions. Metal–metal covalent bonds provide a large perturbation in electronic …

The solar‐driven CO2 reduction is a challenge in the field of “artificial photosynthesis”, as
most catalysts display low activity and selectivity for CO2 reduction in water‐containing …

Bimetallics are emerging as important materials that often exhibit distinct chemical
properties from monometallics. However, there is limited access to homogeneously alloyed …

In this review article, we discuss advances in the chemistry of metal carbonyl clusters
(MCCs) spanning the last three decades, with an emphasis on the more recent reports and …

Activation of inert molecules like CO2 is often mediated by cooperative chemistry between
two reactive sites within a catalytic assembly, the most common form of which is Lewis …

One of the most challenging tasks in organic synthesis is to control selectivities, especially
switching the well-known selectivity to obtain new isomers that were previously inaccessible …

Bimetallic catalysts of nickel (0) with a trivalent rare-earth ion or Ga (III), NiML3 (where L is
[iPr2PCH2NPh]−, and M is Sc, Y, La, Lu, or Ga), were investigated for the selective …