Gold–manganese bimetallic redox coupling with light

S Xia, W Li, H Chen, C Zhu, J Han… - Journal of the American …, 2023 - ACS Publications
The classical Au (I)/Au (III) redox couple chemistry has been limited to constructing C–C and
C–X bonds, and thus, the exploration of the elementary reaction of gold redox coupling is …

Ligand‐Enabled Gold‐Catalyzed Cyanation of Organohalides

A Kumar, N Bhattacharya, MV Mane… - Angewandte Chemie …, 2024 - Wiley Online Library
Herein, we disclose the first report on gold‐catalyzed C (sp2)‐CN cross‐coupling reaction
by employing a ligand‐enabled Au (I)/Au (III) redox catalysis. This transformation utilizes …

Palladium-Catalyzed Dehydrogenative Carbonylative Esterification of Allenoic Acids for the Synthesis of γ-Butyrolactone Derivatives

B Wang, M Ren, N Iqbal, X Mu, JE Backvall… - Organic …, 2024 - ACS Publications
A highly efficient dehydrogenative carbonylative esterification of allenoic acids using Pd-
catalysis was developed, providing a novel approach to synthesizing esterified γ …

Visible light-mediated gold-catalyzed alkynylative cyclization of allenoates with iodoalkynes for the synthesis of β-alkynyl-γ-butenolides

Y He, Y Zhong, MB Marion, JCH Luna, W Ma… - Organic Chemistry …, 2024 - pubs.rsc.org
A method for the tandem cyclization/alkynylation of allenoates with iodoalkynes via gold
catalysis under light irradiation is described. This transformation features a broad substrate …

Electrochemistry and Gold Catalysis: Unusual Allies in Redox Mediated Organic Reactions

C Praveen, GC Clososki - Chemistry–An Asian Journal, 2025 - Wiley Online Library
Devising advanced protocols to avoid harsh oxidants is of paramount interest in gold
catalyzed redox reactions. To address this issue, electrochemical oxidation of precatalytic …

Electrochemical Gold Redox Catalysis

A Kumar, N Bhattacharya, NT Patil - ChemCatChem, 2024 - Wiley Online Library
The high oxidation potential of Au (I)/Au (III) redox couple renders the development of gold‐
catalyzed cross‐coupling reactions highly challenging. In the pursuit of Au (I)/Au (III) redox …

Gold-Catalyzed C(sp3)–C(sp2) Suzuki–Miyaura Coupling Reaction

W Du, F Zhao, R Yang, Z Xia - Organic Letters, 2024 - ACS Publications
A gold-catalyzed C (sp3)–C (sp2) Suzuki–Miyaura coupling reaction facilitated by ligand-
enabled Au (I)/Au (III) redox catalysis was developed. The cross-coupling of alkyl …

Electrochemical Synthesis of Gold‐N‐Heterocyclic Carbene Complexes**

TP Nicholls, Z Jia, JM Chalker - Chemistry–A European …, 2024 - Wiley Online Library
An electrochemical synthesis of gold (I)‐N‐heterocyclic carbene (Au‐NHC) complexes has
been developed. The electrochemical methodology uses only imidazolium salts, gold metal …

Computational photochemistry: advances in 2022–2023

M Navarrete-Miguel, J Cuéllar-Zuquin… - 2024 - books.rsc.org
Computational photochemistry provides a description of light-induced chemical phenomena
reaching the molecular size-scale and femtosecond time-scale resolutions. In the period …

Gold-Catalyzed 1, 2-Carboxyarylation of Alkenes

T Nanda, A Das, P Bera, NT Patil - 2024 - chemrxiv.org
Herein, we have disclosed the gold-catalyzed 1, 2-carboxyarylation of alkenes through the
ligand enabled Au (I)/Au (III) catalysis. Unlike other approaches for arylative functionalization …