Electrochemical behaviour of palladium electrode: Oxidation, electrodissolution and ionic adsorption

M Grdeń, M Łukaszewski, G Jerkiewicz, A Czerwiński - Electrochimica Acta, 2008 - Elsevier
In electrochemistry, Pourbaix diagrams also known as potential-pH diagrams map out the
regions of stability of metals as well as the regions of possible existence of stable …

Hydrogen electrocatalysis

LA Kibler - ChemPhysChem, 2006 - Wiley Online Library
E0 ¼ 0 V versus the standard hydrogen electrode ðSHEÞ ð1Þ needs to be catalysed by an
electronic conductor, that is, it takes place at an electrode surface. A huge variety of possible …

Reactivity of monolayers and nano-islands of palladium on Au (1 1 1) with respect to proton reduction

S Pandelov, U Stimming - Electrochimica Acta, 2007 - Elsevier
Electrochemical reactivity regarding hydrogen reduction was studied at epitaxially grown Pd
monolayers and sub-monolayers on Au (111) in 0.1 M HClO4 solution. The rate of hydrogen …

Metal deposition and electrocatalysis for elucidating structural changes of gold electrodes during cathodic corrosion

MM Elnagar, LA Kibler, T Jacob - Green Chemistry, 2023 - pubs.rsc.org
Several electrochemical conversion reactions occur under high cathodic currents, where
electrocatalysts can experience substantial alterations in their surface structure through …

What vibrational spectroscopy tells about water structure at the electrified palladium–water interface

Y Zhang, ZF Su, JF Li, J Lipkowski - The Journal of Physical …, 2020 - ACS Publications
The knowledge of the structure and properties of water adsorbed on metal surfaces is
relevant for understanding electrocatalytic reactions. A monolayer of Pd deposited at a gold …

Mechanism of hydrogen adsorption/absorption at thin Pd layers on Au (1 1 1)

H Duncan, A Lasia - Electrochimica acta, 2007 - Elsevier
Hydrogen adsorption and absorption at thin palladium deposits of 0.8–10 monolayers (ML)
on Au (111) was studied in 0.1 M H2SO4 and HClO4 using cyclic voltammetry, ac …

Extensive photochemical restructuring of molecule-metal surfaces under room light

C Guo, P Benzie, S Hu, B de Nijs, E Miele… - Nature …, 2024 - nature.com
The molecule-metal interface is of paramount importance for many devices and processes,
and directly involved in photocatalysis, molecular electronics, nanophotonics, and molecular …

Dependence of electrocatalytic activity on film thickness for the hydrogen evolution reaction of Pd overlayers on Au (1 1 1)

LA Kibler - Electrochimica Acta, 2008 - Elsevier
The hydrogen evolution reaction has been studied for ultrathin Pd overlayers of various
thickness on Au (111) in 0.1 M H2SO4. A clear correlation of the electrocatalytic activity as …

Formation of palladium nanofilms using electrochemical atomic layer deposition (E-ALD) with chloride complexation

LB Sheridan, DK Gebregziabiher, JL Stickney… - Langmuir, 2013 - ACS Publications
Pd thin films were formed by electrochemical atomic layer deposition (E-ALD) using surface-
limited redox replacement (SLRR) of Cu underpotential deposits (UPD) on polycrystalline …

Electrocatalytic reduction of nitrite on transition and coinage metals

M Duca, B Van Der Klugt, MTM Koper - Electrochimica Acta, 2012 - Elsevier
A systematic comparison of the electrochemical reduction of nitrite at polycrystalline metals
has been carried out. In acidic media, solution-phase NO from HNO2 decomposition is …