Condensed Osmaquinolines with NIR‐II Absorption Synthesized by Aryl C− H Annulation and Aromatization
FH Cui, Q Li, LH Gao, K Ruan, K Ma… - Angewandte …, 2022 - Wiley Online Library
The structural design and tuning of properties of metallaaromatics are crucial in materials
and energy science. Herein, we describe the rapid synthesis of tetracyclic metallaaromatics …
and energy science. Herein, we describe the rapid synthesis of tetracyclic metallaaromatics …
Synthesis and characterization of bi (metallacycloprop-1-ene) complexes
W Bai, LY Tsang, Y Wang, Y Li, HHY Sung… - Chemical …, 2023 - pubs.rsc.org
In all previously reported metallacycloprop-1-ene or η2-vinyl complexes, the metal center
bears only one vinyl moiety. We have now successfully synthesized and structurally …
bears only one vinyl moiety. We have now successfully synthesized and structurally …
NIR-responsive metal-containing polymer hydrogel for light-controlled microvalve
X Lin, W Xie, Q Lin, Y Cai, Y Hua, J Lin, G He… - Polymer …, 2021 - pubs.rsc.org
Metal-containing polymers have drawn considerable interest because of their unexpected
and fantastic properties, and can be applied for preparing functional hydrogels. However …
and fantastic properties, and can be applied for preparing functional hydrogels. However …
Insertion chemistry of lutetacyclopropene toward unsaturated C− O/C− N bonds
Although the reaction chemistry of transition metallacyclopropenes has been well‐
established in the last decades, the reactivity of rare‐earth metallacyclopropenes remains …
established in the last decades, the reactivity of rare‐earth metallacyclopropenes remains …
Switching the Photoreactions of Ir (III) Diamine Complexes between C–N Coupling and Dehydrogenation under Visible Light Irradiation
XK Huang, LP Li, HY Zhou, MF Xiong, JY Fan… - Inorganic …, 2022 - ACS Publications
The selective photoreactions under mild conditions play an important role in synthetic
chemistry. Herein, efficient and mild protocols for switching the photoreactions of Ir (III) …
chemistry. Herein, efficient and mild protocols for switching the photoreactions of Ir (III) …
Probing σ-Aromaticity-Driven Ring Contraction of Metallabenzocyclobutadiene to Metallabenzocyclopropene
J Xing, YZ Tan, J Zhu - Inorganic Chemistry, 2024 - ACS Publications
Ring contraction of metallacyclobutadiene to metallacyclopropene is rare because of the
increasing strain from a four-membered ring to a three-membered one. Here we …
increasing strain from a four-membered ring to a three-membered one. Here we …
Oxidation-induced coupling reactions of bi (metallacycloprop-1-ene) complexes
LY Tsang, LC Kong, HHY Sung, ID Williams… - Chemical …, 2024 - pubs.rsc.org
The feasibility of coupling of two carbene ligands of biscarbene complexes LnM (CR2) 2 to
form alkene complexes LnM (η2-R2CCR2) was predicted theoretically as early as 1982 …
form alkene complexes LnM (η2-R2CCR2) was predicted theoretically as early as 1982 …
Visible-light-induced amination of quinoline at the C8 position via a postcoordinated interligand-coupling strategy under mild conditions
HL Peng, Y Li, XY Chen, LP Li, Z Ke, BH Ye - Inorganic Chemistry, 2021 - ACS Publications
The postcoordinated interligand-coupling strategy provides a useful and complementary
protocol for synthesizing polydentate ligands. Herein, diastereoselective photoreactions of Λ …
protocol for synthesizing polydentate ligands. Herein, diastereoselective photoreactions of Λ …
Cationic Mononuclear Bi(rhenacyclopropene) Complexes from Reactions of ReCl3(PMePh2)3 with RC≡CH (R=alkyl)
L Li, Y Zhao, Y Zhou, W Bai - Zeitschrift für anorganische und …, 2023 - Wiley Online Library
Reactions of terminal alkynes (alkyl− C≡ CH) and internal alkynes with rhenium (III)
phosphine complex ReCl3 (PMePh2) 3 were studied, producing cationic mononuclear bi …
phosphine complex ReCl3 (PMePh2) 3 were studied, producing cationic mononuclear bi …
Diastereoselective Photoreaction of Ir(III) Amine Complexes for Generation of New Multidentate Ligands in situ via a Postcoordinated Interligand‐Coupling Strategy
XY Chen, SY Yao, LP Li, BH Ye - Chinese Journal of Chemistry, 2021 - Wiley Online Library
Main observation and conclusion The diastereoselective photoreactions of Ir (III)‐amine and
Ir (III)‐diamine complexes are observed in the presence of O2. The Ʌ‐[Ir (pq) 2 (R …
Ir (III)‐diamine complexes are observed in the presence of O2. The Ʌ‐[Ir (pq) 2 (R …