Polymer brushes on flat and curved surfaces: How computer simulations can help to test theories and to interpret experiments

K Binder, A Milchev - Journal of Polymer Science Part B …, 2012 - Wiley Online Library
Theoretical descriptions of static properties of polymer brushes are reviewed, with an
emphasis on monodisperse macromolecules grafted to planar, cylindrical, or spherical …

Normal and shear forces between polymer brushes

GS Grest - Polymers in Confined Environments, 1999 - Springer
Surface-polymer interactions are important in many technological applications, including
colloidal stablization and adherence. Recently there has been considerable progress in …

Swelling of a polymer brush probed with a quartz crystal resonator

A Domack, O Prucker, J Rühe, D Johannsmann - Physical Review E, 1997 - APS
We have studied the temperature dependence of swelling of a polystyrene brush in
cyclohexane with quartz resonators and ellipsometry. The swelling of the layer, which has …

Polymer brushes in solvents of variable quality: Molecular dynamics simulations using explicit solvent

DI Dimitrov, A Milchev, K Binder - The Journal of chemical physics, 2007 - pubs.aip.org
The structure and thermodynamic properties of a system of end-grafted flexible polymer
chains grafted to a flat substrate and exposed to a solvent of variable quality are studied by …

Simulation and modelling of slip flow over surfaces grafted with polymer brushes and glycocalyx fibres

M Deng, X Li, H Liang, B Caswell… - Journal of fluid …, 2012 - cambridge.org
Fabrication of functionalized surfaces using polymer brushes is a relatively simple process
and parallels the presence of glycocalyx filaments coating the luminal surface of our …

Structure, interactions, and dynamics in tethered chain systems

AP Gast - Langmuir, 1996 - ACS Publications
We use the self-assembling nature of diblock copolymers in selective solvents to produce
monodisperse spherical micelles. These micelles provide a valuable model system to study …

Polyelectrolyte spin assembly: influence of ionic strength on the growth of multilayered thin films

CJ Lefaux, JA Zimberlin, AV Dobrynin… - Journal of Polymer …, 2004 - Wiley Online Library
Abstract Layer‐by‐layer (LbL) assembly of polymer electrolyte multilayers is now a well‐
established method for the fabrication of thin films by sequential adsorption of alternating …

Rheology of polymer brushes: A Brownian dynamics study

PS Doyle, ESG Shaqfeh, AP Gast - Macromolecules, 1998 - ACS Publications
We present results of Brownian dynamics simulations of polymer brushes under steady and
oscillatory shear. The brush is sheared by a bare surface and the resulting solvent velocity …

Scaling of polymer solutions as a quantitative tool

AV Dobrynin, M Jacobs, R Sayko - Macromolecules, 2021 - ACS Publications
Knowledge of interaction parameters and Kuhn length for a polymer/solvent pair is a
foundation of polymer physics of synthetic and biological macromolecules. Here, we …

Engineering Surface-Grafted Polymers for Adhesion and Friction Control

Y Zhang, B Yu, S Ma, Y Ma, G Zhang, K Hu… - Progress in Polymer …, 2024 - Elsevier
The last few decades have witnessed the great progress in surface modification through the
use of functional polymer coatings. Surface-grafted polymers with thickness ranging from …