Regiodivergent alkene functionalization that produces either regioisomer starting from the
same raw materials is desirable. Herein, we report a nickel‐catalyzed switchable site …

Linear, α‐branched, and β‐branched aliphatic amines are widespread in pharmaceuticals,
agrochemicals, and fine chemicals. Thus, the development of direct and efficient methods to …

A NiH‐catalyzed migratory hydroalkylation of alkenyl amines with predictable and
switchable regioselectivity is reported. By utilizing a ligand‐controlled, directing group …

Organosilicon compounds have shown tremendous potential in drug discovery and their
synthesis stimulates wide interest. Multicomponent cross-coupling of alkenes with silicon …

Herein, we disclose a Ni-catalyzed 1, 1-difunctionalization of unactivated terminal alkenes
that enables the incorporation of two different heteroatom motifs across an olefin backbone …

The precise control of the regioselectivity in the transition metal‐catalyzed migratory
hydrofunctionalization of alkenes remains a big challenge. With a transient ketimine …

The successful realization of gold‐catalyzed chain‐walking reactions, facilitated by ligand‐
enabled Au (I)/Au (III) redox catalysis, has been reported for the first time. This breakthrough …

As a general method for the synthesis of alcohols, the direct oxygenation of alkenes is
difficult to afford linear alcohols. Herein, we communicate the remote hydro-oxygenation of …

Herein, we disclose an interrupted deaminative Ni-catalyzed chain-walking strategy that
forges sp3–sp3 architectures at remote, yet previously unfunctionalized, methylene sp3 C–H …

Abstract A remote C (sp3)− H bond asymmetric borylation of unactivated alkenes was
achieved by bimetallic relay catalysis. The reaction proceeded through reversible and …